Fire Varnish Basecoat

1.1. Product identifier

Product name: FIRE VARNISH ACTIVATOR NG
Product code: FVTHERMAC

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of substance / mixture: Acid catalyst to be mixed with Fire varnish base NG

1.3. Details of the supplier of the safety data sheet

Company name: Thermoguard UK Ltd
Kirkby Street
Hull
HU2 0HE
United Kingdom

Tel: 01142 768 008
Fax: 01624 825 526
Email: technical@thermoguard.co.uk

2.1. Classification of the substance or mixture

Classification under CLP: Skin Corr. 1B: H314; Met. Corr. 1: H290; Skin Irrit. 2: H315; Eye Dam. 1: H318

Most important adverse effects: May be corrosive to metals. Causes skin irritation. Causes serious eye damage.

2.2. Label elements

Label elements:

Hazard statements: H290: May be corrosive to metals.

H315: Causes skin irritation.

H318: Causes serious eye damage.

Hazard pictograms: GHS05: Corrosion

Signal words: Danger

Precautionary statements: P260: Do not breathe dust/fumes/gas/mist/vapours/spray.

P280: Wear protective gloves/protective clothing/eye protection/face protection.

P303+361+353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.

P304+340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P333+313: If skin irritation or rash occurs: Get medical advice/attention.

P234: Keep only in original container.

P390: Absorb spillage to prevent material damage.

P406: Store in corrosive resistant container with a resistant inner liner.

P264: Wash hands thoroughly after handling.

P310: Immediately call a for instructions/advice.

2.3. Other hazards

PBT: This product is not identified as a PBT/vPvB substance.

3.2. Mixtures

Hazardous ingredients:

PHOSPHORIC ACID PROPYL ESTER
EINECS: –
CAS: 145441-41-4
PBT / WEL: –
CLP Classification: Met. Corr. 1: H290; Skin Irrit. 2: H315; Eye Dam. 1: H318
Percent: 30-50%

ALUMINIUM TRIS(DIHYDROGEN PHOSPHATE) – REACH registered number(s): 01-2119490078-32-0000
EINECS: –
CAS: 13530-50-2
PBT / WEL: –
CLP Classification: Eye Dam. 1: H318
Percent: 10-30%

2-PHENOXYETHANOL
EINECS: 204-589-7
CAS: 122-99-6
PBT / WEL: –
CLP Classification: Acute Tox. 4: H302; Eye Irrit. 2: H319
Percent: 1-10%

ORTHOPHOSPHORIC ACID
EINECS: 231-633-2
CAS: 7664-38-2
PBT / WEL: –
CLP Classification: Skin Corr. 1B: H314
Percent: 1-10%

Non-classified ingredients:

TROYSOL LAC
EINECS: 452-570-9
CAS: –
PBT / WEL: –
CLP Classification: Skin Irrit. 2: H315; Aquatic Chronic 2: H411; Eye Dam. 1: H318; STOT RE 2: H373
Percent: <1%

Contains: aluminium tris(dihydrogen phosphate) phosphoric acid propyl ester

4.1. Description of first aid measures

Skin contact: Remove all contaminated clothes and footwear immediately unless stuck to skin. Drench the affected skin with running water for 10 minutes or longer if substance is still on skin. Transfer to hospital if there are burns or symptoms of poisoning.

Eye contact: Bathe the eye with running water for 15 minutes. seek immediate medical advice

Ingestion: Wash out mouth with water. Do not induce vomiting. If unconscious, check for breathing and apply artificial respiration if necessary. If unconscious and breathing is OK, place in the recovery position. Obtain immediate medical attention

Inhalation: Remove casualty from exposure ensuring one’s own safety whilst doing so. May cause irritation of the respiratory system Keep the patient warm and at rest If unconscious and breathing is OK, place in the recovery position. If conscious, ensure the casualty sits or lies down. If breathing becomes bubbly, have the casualty sit and provide oxygen if available. Consult a doctor.

4.2. Most important symptoms and effects, both acute and delayed

Skin contact: Irritation or pain may occur at the site of contact. Blistering may occur.

Eye contact: Splashes in the eye May cause permanent damage.

Ingestion: Corrosive burns may appear around the lips. Corrosive – even small amounts can cause serious damage

Inhalation: There may be shortness of breath with a burning sensation in the throat. Exposure may cause coughing or wheezing.

Delayed / immediate effects: Immediate effects can be expected after short-term exposure.

4.3. Indication of any immediate medical attention and special treatment needed

Immediate / special treatment: Eye bathing equipment should be available on the premises. Show this safety data sheet to the doctor in attendance.

5.1. Extinguishing media

Extinguishing media: Suitable extinguishing media for the surrounding fire should be used. Carbon dioxide. Alcohol resistant foam. Dry chemical powder. Water fog. Use water spray to cool containers.

5.2. Special hazards arising from the substance or mixture

Exposure hazards: Corrosive. In combustion emits toxic fumes.

5.3. Advice for fire-fighters

Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes. Do not allow run off to enter watercourses or drains.

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions: Avoid breathing any vapours Ventilate the area. Exclude all non essential personnel. Do not attempt to take action without suitable protective clothing – see section 8 of SDS. Turn leaking containers leak-side up to prevent the escape of liquid.

6.2. Environmental precautions

Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding.

6.3. Methods and material for containment and cleaning up

Clean-up procedures: Absorb into dry earth or sand. Remove mechanically Transfer to a closable, labelled salvage container for disposal by an appropriate method. neutralise residue with soda and rinse with plenty of water

6.4. Reference to other sections

Reference to other sections: Refer to section 8 of SDS.

7.1. Precautions for safe handling

Handling requirements: Avoid direct contact with the substance. Wear protective gloves,eye and face protection. Ensure there is sufficient ventilation of the area. Do not handle in a confined space. Smoking, eating and drinking should be prohibited in mixing and application area. Avoid direct contact with the substance. Avoid the formation or spread of mists in the air. Always wash your hands before eating, smoking or using the toilet

7.2. Conditions for safe storage, including any incompatibilities

Storage conditions: Store in a cool, well ventilated area. Keep out of reach of children Keep container tightly closed. observe label precautions

Suitable packaging: Must only be kept in original packaging.

7.3. Specific end use(s)

Specific end use(s): the identified uses of this product are detailed in section 1 refer to Application Instructions before using this product Acid Component Part A for Use with Fire Varnish Resin Base Part B.

8.1. Control parameters

Hazardous ingredients:

DNEL/PNEC Values

Hazardous ingredients:

8.2. Exposure controls

Engineering measures: Ensure there is sufficient ventilation of the area.

Respiratory protection: in case of insufficient ventilation suitable respiratory equipment should be used. Respiratory protection must be used if the general level exceeds the recommended occupational exposure limit Air fed mask fitted with appropiate filters must be used when spraying. Self-contained breathing apparatus must be available in case of emergency.

Hand protection: Impermeable gloves. the instructions and information provided by the glove manufacturer on use storage maintenance and replacement must be followed

Eye protection: Safety glasses with side-shields. manufactured and tested to EN 166and designed to protect against splashes Ensure eye bath is to hand.

Skin protection: Impermeable protective clothing.

Environmental: Prevent from entering in public sewers or the immediate environment. Handle in accordance with good industrial hygiene and safety practices.

9.1. Information on basic physical and chemical properties

State: Liquid

Colour: Dark brown

Odour: Characteristic odour

Evaporation rate: not determined

Solubility in water: dispersible in water

Boiling point/range°C: 100

Melting point/range°C: No data available.

Flammability limits %: lower: No data available. upper: No data available.

Flash point°C: No data available.

Part.coeff. n-octanol/water: No data available.

Autoflammability°C: No data available.

Relative density: 1.35 -1.45

pH: 1-2

9.2. Other information

Other information: Refer to Fire Varnish Application instuctions before using Pot life when mixed approximately 2 hours dependant on Temperature,Humidity and season of the year.

10.1. Reactivity

Reactivity: Stable under recommended transport or storage conditions.

10.2. Chemical stability

Chemical stability: Stable under normal conditions.

10.3. Possibility of hazardous reactions

Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions.

Decomposition may occur on exposure to conditions or materials listed below.

10.4. Conditions to avoid

Conditions to avoid: Heat.

10.5. Incompatible materials

Materials to avoid: Strong oxidising agents. Strong bases. exothermic reaction

10.6. Hazardous decomposition products

Haz. decomp. products: In combustion emits toxic fumes.

11.1. Information on toxicological effects

Hazardous ingredients:

Symptoms / routes of exposure

Skin contact: Irritation or pain may occur at the site of contact. Blistering may occur.

Eye contact: Splashes in the eye May cause permanent damage.

Ingestion: Corrosive burns may appear around the lips. Corrosive – even small amounts can cause serious damage.

Inhalation: There may be shortness of breath with a burning sensation in the throat. Exposure may cause coughing or wheezing.

Delayed / immediate effects: Immediate effects can be expected after short-term exposure.

Other information: In all cases of doubt or where symptons persist obtain medical attention formaldehyde  is released during curing. it is irritating to the mucous membraines and may cause skin sensitisation.

12.1. Toxicity

Ecotoxicity values: No data available.

12.2. Persistence and degradability

Persistence and degradability: No data available.

12.3. Bioaccumulative potential

Bioaccumulative potential: No data available.

12.4. Mobility in soil

Mobility: No data available.

12.5. Results of PBT and vPvB assessment

PBT identification: This product is not identified as a PBT/vPvB substance.

12.6. Other adverse effects

Other adverse effects: No data available.

13.1. Waste treatment methods

Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal company.

Waste code number: 08 01 12

Disposal of packaging: Drained and rigorously scraped out empty containers are controlled wastes and should be disposed of according with the regulations made under the Control of Pollution Act and Enviromental Protection Act

NB: The user’s attention is drawn to the possible existence of regional or national regulations regarding disposal.

14.1. UN number

UN number: UN3265

14.2. UN proper shipping name

Shipping name: Corrosive liquid,Acidic Organic,n.o.s.(Phosphoric Acid propyl ester,Phosphoric Acid

14.3. Transport hazard class(es)

Transport class: 8

14.4. Packing group

Packing group: 111

14.5. Environmental hazards

Environmentally hazardous: No

Marine pollutant: No

14.6. Special precautions for user

Special precautions: Always transport in upright sealed containers Ensure that persons transporting the product what to do in the event of an accident or spillage

Tunnel code: E

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

Transport in bulk: not Relevant

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Specific regulations: The provisions of the Health and Safety at Work Act and the Control of Substances Hazardous to Health Regulations apply to this product

15.2. Chemical Safety Assessment

Chemical safety assessment: A chemical safety assessment has not been carried out for the substance or the mixture by the supplier.

Other information

Other information: This safety data sheet has been prepared in accordance with Regulation(EC) No 1907/2006 REACH

This safety data sheet is prepared in accordance with Commission Regulation (EC) No 1272/2008.

* indicates text in the SDS which has changed since the last revision.

Phrases used in s.2 and s.3: H290: May be corrosive to metals.

H302: Harmful if swallowed.

H314: Causes severe skin burns and eye damage.

H315: Causes skin irritation.

H318: Causes serious eye damage.

H319: Causes serious eye irritation.

H373: May cause damage to organs through prolonged or repeated exposure .

H411: Toxic to aquatic life with long lasting effects.

Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product.

1.1. Product identifier

Product name: * FIRE VARNISH BASE NG
Product code: * FVTHERMBA

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of substance / mixture: Resin component of Clear Fire Varnish.To be mixed with Fire Varnish Activator part A to produce a liquid air drying clear varnish for the coating of timber. applied by brush,roller or spray For professional and industrial use only.

1.3. Details of the supplier of the safety data sheet

Company name: Thermoguard UK Ltd
Kirkby Street
Hull
HU2 0HE
United Kingdom

Tel: 01142 768 008
Fax: 01624 825 526
Email: technical@thermoguard.co.uk

1.4. Emergency telephone number

Emergency tel: 01624 825 115 (office hours only)

2.1. Classification of the substance or mixture

Classification under CLP: Carc. 1B: H350; Skin Sens. 1: H317

Most important adverse effects: May cause an allergic skin reaction. May cause cancer route not known.

2.2. Label elements

Label elements:

Hazard statements: H317: May cause an allergic skin reaction.

H350: May cause cancer route not known.

Hazard pictograms: GHS07: Exclamation mark

GHS08: Health hazard

Signal words: Danger

Precautionary statements: P201: Obtain special instructions before use.

P202: Do not handle until all safety precautions have been read and understood.

P280: Wear protective gloves/protective clothing/eye protection/face protection.

P302+352: IF ON SKIN: Wash with plenty of water/.

P308+313: IF exposed or concerned: Get medical advice/attention.

P321: Specific treatment (see medical advice on this label).

2.3. Other hazards

Other hazards: Danger of serious damage to health by prolonged exposure.

PBT: This product is not identified as a PBT/vPvB substance.

3.2. Mixtures

Hazardous ingredients:

Contains: * Formaldehyde methanol

4.1. Description of first aid measures

Skin contact: Remove all contaminated clothes and footwear immediately unless stuck to skin.

Consult a doctor. Drench the affected skin with running water for 10 minutes or longer if substance is still on skin.

Eye contact: Bathe the eye with running water for 15 minutes. Consult a doctor.

Ingestion: Wash out mouth with water. Consult a doctor.

Inhalation: Remove casualty from exposure ensuring one’s own safety whilst doing so. Give nothing by mouth If unconscious and breathing is OK, place in the recovery position. Consult a doctor.

4.2. Most important symptoms and effects, both acute and delayed

Skin contact: There may be irritation and redness at the site of contact.

Eye contact: There may be irritation and redness. The eyes may water profusely.

Ingestion: There may be soreness and redness of the mouth and throat.

Inhalation: Exposure to organic solvent vapours in excess of stated occupational exposure limits may result in adverse health effects There may be irritation of the throat. Exposure may cause coughing or wheezing.

Delayed / immediate effects: Exposure to organic solvent vapours in excess of the stated occupational exposure limit may result in adverse health effects Repeated or prolonged contact with the product may cause removal of natural oils and fats from the skin

4.3. Indication of any immediate medical attention and special treatment needed

Immediate / special treatment: In all cases of doubt,or when symptoms persist seek medical attention. Show this safety data sheet to the doctor in attendance.

5.1. Extinguishing media

Extinguishing media: Suitable extinguishing media for the surrounding fire should be used. Alcohol resistant foam. Carbon dioxide. Dry chemical powder. Water spray. Use water spray to cool containers.

5.2. Special hazards arising from the substance or mixture

Exposure hazards: In the event of Fire and/or explosion do NOT breathe Fumes. In combustion emits toxic fumes.

5.3. Advice for fire-fighters

Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes. Do not allow run off to enter watercourses or drains.

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions: Do not attempt to take action without suitable protective clothing – see section 8 of SDS. Turn leaking containers leak-side up to prevent the escape of liquid. Evacuate the area immediately.

6.2. Environmental precautions

Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding. If the product enters Drains or Water courses, the local water company should be contacted immediately.

6.3. Methods and material for containment and cleaning up

Clean-up procedures: Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal by an appropriate method. Clean-up should be dealt with only by qualified personnel familiar with the specific substance.

6.4. Reference to other sections

Reference to other sections: Refer to section 8 of SDS. Refer to section 13 of SDS.

7.1. Precautions for safe handling

Handling requirements: Avoid direct contact with the substance. Avoid the formation or spread of mists in the air. Ensure there is sufficient ventilation of the area. Always wash your hands before eating, smoking or using the toilet Smoking ,eating and drinking should be prohibited in mixing and application area In case of insufficient ventilation wear suitable respiratory protection.

7.2. Conditions for safe storage, including any incompatibilities

Storage conditions: observe label precautions Store in a cool, well ventilated area. Keep container tightly closed.

Suitable packaging: Must only be kept in original packaging.

7.3. Specific end use(s)

Specific end use(s): the identified uses of this product are detailed in section 1 refer to Application Instructions before using this product.

8.1. Control parameters

Hazardous ingredients:

DNEL/PNEC Values

Hazardous ingredients:

8.2. Exposure controls

Engineering measures: Ensure there is sufficient ventilation of the area. where practical by use of local exhaust ventilation

Respiratory protection: Self-contained breathing apparatus must be available in case of emergency. Respiratory protection must be used if the general level exceeds the recommended occupational exposure limit Air fed mask fitted with appropiate filters must be used when spraying.

Hand protection: Impermeable gloves. the instructions and information provided by the glove manufacturer on use storage maintenance and replacement must be followed

Eye protection: Safety glasses. manufactured and tested to EN 166and designed to protect against splashes Ensure eye bath is to hand.

Skin protection: Impermeable protective clothing.

Environmental: Handle in accordance with good industrial hygiene and safety practices Prevent from entering in public sewers or the immediate environment.

9.1. Information on basic physical and chemical properties

State: Liquid

Colour: water-white

Odour: formaldehyde-like

Evaporation rate: No data available.

Oxidising: No data available.

Solubility in water: Miscible

Viscosity: Viscous

Kinematic viscosity: 5.5-7.5 p

Viscosity test method: rotothinner@20oC

Boiling point/range°C: 100oC

Melting point/range°C: Not applicable.

Flammability limits %: lower: No data available. upper: No data available.

Flash point°C: Not applicable.

Part.coeff. n-octanol/water: No data available.

Autoflammability°C: No data available.

Vapour pressure: No data available.

Relative density: 1.2-1.3 pH: Approx. 8.5-9.5

VOC g/l: 26 g/l

9.2. Other information

Other information: Please read information on the labels before using Refer to Fire Varnish Application instuctions before using Pot life when mixed approximately 2 hours dependant on Temperature, Humidity and season of the year.

10.1. Reactivity

Reactivity: Stable under recommended transport or storage conditions.

10.2. Chemical stability

Chemical stability: Stable under normal conditions.

10.3. Possibility of hazardous reactions

Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions. Decomposition may occur on exposure to conditions or materials listed below.

10.4. Conditions to avoid

Conditions to avoid: Heat. Hot surfaces. Flames.

10.5. Incompatible materials

Materials to avoid: Strong oxidising agents. Strong acids.

10.6. Hazardous decomposition products

Haz. decomp. products: In combustion emits toxic fumes.

11.1. Information on toxicological effects

Toxicity values:

Hazardous ingredients:

Symptoms / routes of exposure

Skin contact: There may be irritation and redness at the site of contact.

Eye contact: There may be irritation and redness. The eyes may water profusely.

Ingestion: There may be soreness and redness of the mouth and throat.

Inhalation: Exposure to organic solvent vapours in excess of stated occupational exposure limits may result in adverse health effects There may be irritation of the throat. Exposure may cause coughing or wheezing.

Delayed / immediate effects: Exposure to organic solvent vapours in excess of the stated occupational exposure limit may result in adverse health effects Repeated or prolonged contact with the product may cause removal of natural oils and fats from the skin

Other information: Repeated or Prolonged contact with the product may lead to the removal of natural fats from the skin, resulting non allergic contact dermatitis and absorption through the skin. formaldehyde is released during curing. it is irritating to the mucous membraines and may cause skin sensitisation In all cases of doubt or where symptons persist obtain medical attention.

12.1. Toxicity

Ecotoxicity values: No data available.

12.2. Persistence and degradability

Persistence and degradability: Biodegradable.

12.3. Bioaccumulative potential

Bioaccumulative potential: No bioaccumulation potential.

12.4. Mobility in soil

Mobility: Readily absorbed into soil.

12.5. Results of PBT and vPvB assessment

PBT identification: This product is not identified as a PBT/vPvB substance.

12.6. Other adverse effects

Other adverse effects: Negligible ecotoxicity.

13.1. Waste treatment methods

Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal company.

Waste code number: 08 01 12

Disposal of packaging: Drained and rigorously scraped out empty containers are controlled wastes and should be disposed of according with the regulations made under the Control of Pollution Act and Enviromental Protection Act

NB: The user’s attention is drawn to the possible existence of regional or national regulations regarding disposal.

Transport class: This product does not require a classification for transport.

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Specific regulations: regulation(EC) No 1907/2006 of the European parliament and the council of 18 December 2006 concerning the Registration,Evaluation, Authorisation and restriction of Chemicals (REACH) Regulation(EC) N0 1272/2008 of the European parliament and Council on 18 December 2008 on Classification,labelling,packaging of substances and mixtures(as amended).

15.2. Chemical Safety Assessment

Chemical safety assessment: A chemical safety assessment has not been carried out for the substance or the mixture by the supplier.

Other information

Other information: This safety data sheet is prepared in accordance with Commission Regulation (EC) No 1272/2008.

* indicates text in the SDS which has changed since the last revision.

Phrases used in s.2 and s.3: H225: Highly flammable liquid and vapour.

H301: Toxic if swallowed.

H311: Toxic in contact with skin.

H314: Causes severe skin burns and eye damage.

H317: May cause an allergic skin reaction.

H331: Toxic if inhaled.

H341: Suspected of causing genetic defects .

H350: May cause cancer .

H370: Causes damage to organs .

Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product.