Project Description

High Build Metal Primer – These primers are spirit based and are designed for use on steel and similar substrates.

Supplied as DARK GREY or RED.

Please refer to Thermoguard Technical Department for specific instructions regarding use of these products with fire resistant and fire retardant products.

See Data Sheets and additional information below

AVAILABLE IN:
2.5 & 5 litre packs

THERMOGUARD FLAME RETARDANT WB STEEL TOPCOAT & PRIMER

1.1. Product identifier

Product name TH/P201 – HIGH BUILD METAL PRIMER PRIMER DARK GREY
Product No. TH/P201/224

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses Paint.

1.3. Details of the supplier of the safety data sheet

Supplier THERMOGUARD UK LTD
Kirkby Street
Hull
HU2 0BE
+44(0)1142 768008
+44(0)1624 825115
sales@thermoguard.co.uk
Contact Person Sales Department – 08.00 – 17.00 hrs Mon – Fri. as above

1.4. Emergency telephone number

+44 (0) 1142 768008 Thermoguard UK Ltd (08.00 – 17.00 hrs Mon – Fri)

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)
Physical and Chemical Hazards Flam. Liq. 3 – H226
Human health EUH066;STOT SE 3 – H336
Environment Aquatic Acute 1 – H400;Aquatic Chronic 1 – H410
Classification (1999/45/EEC) N;R50/53. R10, R66, R67.

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

2.2. Label elements

Label In Accordance With (EC) No. 1272/2008

  

Signal Word: Warning

Hazard Statements:

H226 Flammable liquid and vapour.

H336 May cause drowsiness or dizziness.

H410 Very toxic to aquatic life with long lasting effects.

Precautionary Statements:

P102 Keep out of reach of children.

P101 If medical advice is needed, have product container or label at hand.

P271 Use only outdoors or in a well-ventilated area.

P273 Avoid release to the environment.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P501A Dispose of contents/container to special waste collection point

Supplementary Precautionary Statements:

P210 Keep away from heat/sparks/open flames/hot surfaces. – No smoking.

P233 Keep container tightly closed.

P240 Ground/bond container and receiving equipment.

P241 Use explosion-proof electrical equipment.

P242 Use only non-sparking tools.

P243 Take precautionary measures against static discharge.

P261 Avoid breathing vapour/spray.

P370+378 In case of fire: Use foam, carbon dioxide, dry powder or water fog for extinction.

P303+361+353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.

P304+340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P312 Call a POISON CENTER or doctor/physician if you feel unwell.

P391 Collect spillage.

P403+233 Store in a well-ventilated place. Keep container tightly closed.

P403+235 Store in a well-ventilated place. Keep cool.

P405 Store locked up.

Supplemental label information:

EUH066 Repeated exposure may cause skin dryness or cracking.

EUH208 Contains 2-BUTANONE OXIME,Cobalt containing polymer. May produce an allergic reaction.

2.3. Other hazards

3.2. Mixtures

Calcium Carbonate 10-30%
CAS-No.: 1317-65-3
EC No.: 215-279-6
Classification (67/548/EEC): Not classified.
Classification (EC 1272/2008): Not classified.

WHITE SPIRIT 10-30%
CAS-No.:
EC No.: 919-446-0
Classification (67/548/EEC):
Xn;R65.
N;R51/53.
R10,R66,R67.
Classification (EC 1272/2008):
Flam. Liq. 3 – H226
EUH066
STOT SE 3 – H336
STOT RE 1 – H372
Asp. Tox. 1 – H304
Aquatic Chronic 2 – H411
Registration Number: 01-2119458049-33-XXXX

Titanium Dioxide 10-30%
CAS-No.: 13463-67-7
EC No.: 236-675-5
Classification (67/548/EEC): Not classified.
Classification (EC 1272/2008): Not classified.
Registration Number: 01-2119489379-17-xxxx

Diatomaceous Earth 1-5%
CAS-No.: 61790-53-2
EC No.: 310-127-6
Classification (67/548/EEC): Not classified.
Classification (EC 1272/2008): Not classified.

TRIZINC BIS(ORTHOPHOSPHATE) 1-5%
CAS-No.: 7779-90-0
EC No.: 231-944-3
Classification (67/548/EEC): N;R50/53
Classification (EC 1272/2008):
Aquatic Acute 1 – H400
Aquatic Chronic 1 – H410
Registration Number: 01-2119485044-40-0000

Low Aromatic White Spirit 1-5%
CAS-No.:
EC No.: 919-857-5
Classification (67/548/EEC):
Xn;R65.
R10,R66,R67.
Classification (EC 1272/2008):
Flam. Liq. 3 – H226
EUH066
STOT SE 3 – H336
Asp. Tox. 1 – H304
Registration Number: 01-2119463258-33-XXXX

Cobalt containing polymer <1% CAS-No.: EC No.: Classification (67/548/EEC): R43. Classification (EC 1272/2008): Skin Sens. 1 - H317 Low Aromatic White Spirit <1% CAS-No.: 64742-48-9 EC No.: 265-150-3 Classification (67/548/EEC): Xn;R65. R10. Classification (EC 1272/2008): Flam. Liq. 3 - H226 Asp. Tox. 1 - H304 Registration Number: 01-2119457273-39 Yellow Iron Oxide <1% CAS-No.: 51274-00-1 EC No.: Classification (67/548/EEC): Not classified. Classification (EC 1272/2008): Not classified. Registration Number: 01-2119454754-33-xxxx 2-BUTANONE OXIME <1% CAS-No.: 96-29-7 EC No.: 202-496-6 Classification (67/548/EEC): Carc. Cat. 3;R40 Xn;R21 R43 Xi;R41 Classification (EC 1272/2008): Acute Tox. 4 - H312 Eye Dam. 1 - H318 Skin Sens. 1 - H317 Carc. 2 - H351 Registration Number: 01-2119539477-28 Hydrocarbons, C9, aromatics <1% CAS-No.: EC No.: 918-668-5 Classification (67/548/EEC): Xn;R65. Xi;R37. N;R51/53. R10,R66,R67. Classification (EC 1272/2008): Flam. Liq. 3 - H226 EUH066 STOT SE 3 - H335, H336 Asp. Tox. 1 - H304 Aquatic Chronic 2 - H411 Registration Number: 01-2119455851-35-xxxx Zinc Oxide <1% CAS-No.: 1314-13-2 EC No.: 215-222-5 Classification (67/548/EEC): N;R50/53. Classification (EC 1272/2008): Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410 Registration Number: 01-2119463881-32 2-METHYLPENTANE-2,4-DIOL <0.1% CAS-No.: 107-41-5 EC No.: 203-489-0 Classification (67/548/EEC): Xi;R36/38 Classification (EC 1272/2008): Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Carbon Black <0.1% CAS-No.: 1333-86-4 EC No.: 215-609-9 Classification (67/548/EEC): Not classified. Classification (EC 1272/2008): Not classified. Registration Number: 01-2119384822-32 ZIRCONIUM SALT, 2-ETHYLHEXANOIC ACID <0.1% CAS-No.: 22464-99-9 EC No.: 245-018-1 Classification (67/548/EEC): Repr. Cat. 3;R63. Classification (EC 1272/2008): Repr. 2 - H361d Registration Number: 01-2119979088-21-0002 The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. XYLENE, MIXED ISOMERS <0.1% CAS-No.: 1330-20-7 EC No.: 215-535-7 Classification (67/548/EEC): Xn;R20/21,R65. Xi;R36/37/38. R10. Classification (EC 1272/2008): Flam. Liq. 3 - H226 Acute Tox. 4 - H312 Acute Tox. 4 - H332 Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 STOT SE 3 - H335 STOT RE 2 - H373 Asp. Tox. 1 - H304 Registration Number: 01-2119488216-32-xxxx ZIRCONIUM PROPIONATE <0.1% CAS-No.: 84057-80-7 EC No.: 281-897-8 Classification (67/548/EEC): Not classified. Classification (EC 1272/2008): Not classified. Registration Number: 01-2119978305-30-0000 ETHANOL <0.1% CAS-No.: 64-17-5 EC No.: 200-578-6 Classification (67/548/EEC): F;R11 Classification (EC 1272/2008): Flam. Liq. 2 - H225 Registration Number: 01-2119457610-43-xxxx 2,6-Di-tert-butyl-p-cresol <0.1% CAS-No.: 128-37-0 EC No.: 204-881-4 Classification (67/548/EEC): N;R50/53. Classification (EC 1272/2008): Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410 Registration Number: 01-2119565113-46-xxxx [/fusion_toggle][fusion_toggle title="SECTION 4: FIRST AID MEASURES" open="no"]

4.1. Description of first aid measures

General information: General first aid, rest, warmth and fresh air. Do not give victim anything to drink if they are unconscious.

Inhalation: Remove victim immediately from source of exposure. Provide rest, warmth and fresh air. Get medical attention if any discomfort continues. Place unconscious person on the side in the recovery position and ensure breathing can take place.

Ingestion: DO NOT induce vomiting. Get medical attention immediately. Provide fresh air, warmth and rest, preferably in comfortable upright sitting position.

Skin contact: Remove affected person from source of contamination. Remove contaminated clothing immediately and wash skin with soap and water.

Eye contact: Make sure to remove any contact lenses from the eyes before rinsing. Continue to rinse for at least 15 minutes and get medical attention.

4.2. Most important symptoms and effects, both acute and delayed

General information: If adverse symptoms develop as described the casualty should be transferred to hospital as soon as possible.

4.3. Indication of any immediate medical attention and special treatment needed

No specific first aid measures noted.

5.1. Extinguishing media

Extinguishing media: Extinguish with foam, carbon dioxide, dry powder or water fog. Do not use water jet as an extinguisher, as this will spread the fire.

5.2. Special hazards arising from the substance or mixture

Unusual Fire & Explosion Hazards: FLAMMABLE. Solvent vapours may form explosive mixtures with air.

Specific hazards: When heated and in case of fire, harmful vapours/gases may be formed.

5.3. Advice for firefighters

Special Fire Fighting Procedures: Be aware of danger for fire to re-start. Cool containers exposed to flames with water until well after the fire is out. Do not allow runoff to sewer, waterway or ground.

Protective equipment for fire-fighters: Selection of respiratory protection for fire fighting: follow the general fire precautions indicated in the workplace.

6.1. Personal precautions, protective equipment and emergency procedures

Avoid inhalation of vapours and contact with skin and eyes. Provide adequate ventilation. Do not smoke, use open fire or other sources of ignition. Ensure suitable personal protection (including respiratory protection) during removal of spillages in a confined area.

6.2. Environmental precautions

Do not discharge into drains, water courses or onto the ground. Contain spillages with sand, earth or any suitable adsorbent material. Spillages or uncontrolled discharges into watercourses must be IMMEDIATELY alerted to the Environmental Agency or other appropriate regulatory body.

6.3. Methods and material for containment and cleaning up

Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate. Should be prevented from entering drains. Absorb in vermiculite, dry sand or earth and place into containers. Collect spillage in containers, seal securely and deliver for disposal according to local regulations.

6.4. Reference to other sections

For personal protection, see section 8.

7.1. Precautions for safe handling

Observe occupational exposure limits and minimise the risk of inhalation of vapours and mist. Keep away from heat, sparks and open flame. Avoid spilling, skin and eye contact. Ventilate well, avoid breathing vapours. Use approved respirator if air contamination is above accepted level. Do not eat, drink or smoke when using the product. The Manual Handling Operations Regulations may apply to the handling of containers of this product. To assist employers, the following method of calculating the weight for any pack size is given. Take the pack size volume in litres and multiply this figure by the specific gravity value given in section 9. This will give the net weight of the coating in kilograms. Allowance will then have to be made for the immediate packaging to give an approximate gross weight.

7.2. Conditions for safe storage, including any incompatibilities

Store in closed original container at temperatures between 5°C and 25°C. Keep away from heat, sparks and open flame. Keep containers tightly closed. Keep upright. Store separated from: Oxidising material. Alkalis. Acids.

Storage Class: Flammable liquid storage. The storage and use of this product is subject to the Dangerous Substances and Explosive Atmospheres Regulations (DSEAR). The requirements are given in the HSE Approved Code of Practice and Guidance, Storage od Danderous Substances: DSEAR. Up to 250 litres of liquids with a flashpoint above 32C but below 55C may be kept in a workroom provided they are kept in closed containers in a marked, fire-resisting cupboard or bin. Larger quantities must be kept in a separate , marked storeroom conforming to the structural requirements contained in the HSE guidance note Storage of Flammable Liquids in Containers.

7.3. Specific end use(s)

The identified uses for this product are detailed in Section 1.2.

Usage Description: Ensure that waste and contaminated materials are collected and removed from the work area as soon as possible in a suitably labelled container.

8.1. Control parameters

WEL = Workplace Exposure Limit.
Sk = Can be absorbed through skin.

8.2. Exposure controls

Protective equipment: Goggles & Gloves

Engineering measures: Provide adequate ventilation, including appropriate local extraction, to ensure that the defined occupational exposure limit is not exceeded.

Respiratory equipment: No specific recommendation made, but respiratory protection must be used if the general level exceeds the recommended occupational exposure limit.

Hand protection: Use suitable protective gloves if risk of skin contact. The most suitable glove must be chosen in consultation with the gloves supplier, who can inform about the breakthrough time of the glove material. Barrier cream applied before work may make it easier to clean the skin after exposure, but does not prevent absorption through the skin.

Eye protection: Wear splash-proof eye goggles to prevent any possibility of eye contact.

Other Protection: Wear appropriate clothing to prevent reasonably probable skin contact.

Hygiene measures: No specific hygiene procedures noted, but good personal hygiene practices are always advisable, especially when working with chemicals.

9.1. Information on basic physical and chemical properties

Appearance: Viscous Coloured liquid.
Colour: Grey.
Odour: of solvents
Solubility: Insoluble in water
Relative density: @ 20 1.30 approx.
Vapour density (air=1): heavier than air
Viscosity: 3.5 (Rotothinner) Ps @ 25
Flash point (°C): 38 approx. CC (Closed cup).

9.2. Other information

10.1. Reactivity

There are no known reactivity hazards associated with this product.

10.2. Chemical stability

Stable under normal temperature conditions and recommended use.

10.3. Possibility of hazardous reactions

Not determined.

10.4. Conditions to avoid

Avoid contact with water. Avoid heat, flames and other sources of ignition. Avoid contact with acids and oxidising substances. Exothermic reaction with amines and alcohols; reacts slowly with water forming CO2, in closed containers risk of bursting owing to increase of pressure.

10.5. Incompatible materials

Materials To Avoid: Strong alkalis. Strong acids. Strong oxidising substances.

10.6. Hazardous decomposition products

Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours.

11.1. Information on toxicological effects

Inhalation: Vapour from this chemical can be hazardous when inhaled. Vapour may irritate respiratory system or lungs.

Ingestion: Liquid irritates mucous membranes and may cause abdominal pain if swallowed.

Skin contact: Acts as a defatting agent on skin. May cause cracking of skin, and eczema. Prolonged or repeated exposure may cause severe irritation.

Eye contact: May cause temporary eye irritation.

Health Warnings: This product has low toxicity. Only large volumes may have adverse impact on human health.

Route of entry: Inhalation. Skin absorption. Ingestion. Skin and/or eye contact.

Medical Considerations: Skin disorders and allergies. Avoid vomiting and normal rinse of stomach because of risk of aspiration.

Toxicological information on ingredients.

Acute toxicity:
Acute Toxicity (Oral LD50) > 5000 mg/kg Rat
Acute Toxicity (Dermal LD50) > 5000 mg/kg Rabbit
Acute Toxicity (Inhalation LC50) > 5 mg/l (vapours) Rat 4 hours

Skin Corrosion/Irritation:
Erythema\eschar score: Very slight erythema -barely perceptible (1). Well defined erythema (2).
Oedema score: No oedema (0).
Slightly irritating.

Serious eye damage/irritation:
Not Irritating.

Respiratory or skin sensitisation:
Not sensitising.
Skin sensitisation
Guinea pig maximization test (GPMT): Guinea Pig
Not Sensitising.

Germ cell mutagenicity:
Genotoxicity – In Vitro
Chromosome aberration: Negative.
This substance has no evidence of mutagenic properties.

Carcinogenicity:
Inhalation. Rat
This substance has no evidence of carcinogenic properties. Does not contain any substances known to be carcinogenic.

Reproductive Toxicity:
Reproductive Toxicity – Fertility
Fertility: Inhalation. Rat
This substance has no evidence of toxicity to reproduction.
Reproductive Toxicity – Development
Developmental toxicity: Inhalation. Rat
This substance has no evidence of toxicity to reproduction.

Specific target organ toxicity – repeated exposure:
STOT – Repeated exposure: Not available.

Aspiration hazard:
Viscosity: Kinematic viscosity <= 20.5 mm2/s. Inhalation: Vapours may cause drowsiness and dizziness. Central nervous system depression. Ingestion: Harmful: danger of serious damage to health by prolonged exposure if swallowed. Skin contact: Acts as a defatting agent on skin. May cause cracking of skin, and eczema. Eye contact: No specific health warnings noted. Route of entry: Inhalation. Ingestion.

WHITE SPIRIT

Other Health Effects: This substance has no evidence of carcinogenic properties.

Acute toxicity:
Acute Toxicity (Oral LD50) > 15000 mg/kg Rat
Conclusive data but not sufficient for classification.
Acute Toxicity (Dermal LD50) ~ 3400 mg/kg Rabbit
Conclusive data but not sufficient for classification.
Acute Toxicity (Inhalation LC50) > 13.1 mg/l (vapours) Rat 4 hours
Conclusive data but not sufficient for classification.
ATE (Inhalation) 13.1 mg/l (vapours)

Skin Corrosion/Irritation:
Erythema\eschar score: Very slight erythema -barely perceptible (1).
Oedema score: Very slight oedema -barely perceptible (1).
Not irritating.
Not irritating. Non Corrosive to skin.

Serious eye damage/irritation:
Not Irritating.

Respiratory or skin sensitisation:
Respiratory sensitisation: Inconclusive data.
There is evidence that the material can lead to respiratory hypersensitivity.
Skin sensitisation
Guinea pig maximization test (GPMT): Guinea Pig
Not Sensitising.

Germ cell mutagenicity:
Genotoxicity – In Vitro
Bacterial Reverse Mutation Test
Negative.
This substance has no evidence of mutagenic properties.
Genotoxicity – In Vivo
Chromosome aberration:
Negative.

Carcinogenicity:
Carcinogenicity
NOAEL 300 mg/kg Oral Rat
NOAEL >2200 mg/m3 Inhalation. Rat

Reproductive Toxicity:
Reproductive Toxicity – Fertility
One-generation study: NOAEL >3000 mg/kg/day Oral Rat P
Reproductive Toxicity – Development
Developmental toxicity: NOAEC >300 ppm Inhalation. Rat

Specific target organ toxicity – single exposure:
Target Organs: Central nervous system
Central nervous system depression including narcotic effects such as drowsiness, narcosis, reduced alertness, loss of reflexes, lack of coordination and vertigo.

Specific target organ toxicity – repeated exposure:
STOT – Repeated exposure
NOAEL 1056 mg/kg Oral Rat
Target Organs: Central nervous system

Aspiration hazard:
Viscosity: Kinematic viscosity <= 20.5 mm2/s. Inhalation: Vapours may cause drowsiness and dizziness. Ingestion: Harmful: may cause lung damage if swallowed. May cause stomach pain or vomiting. Skin contact: May cause defatting of the skin, but is not an irritant. Not a skin sensitiser. Eye contact: No specific health warnings noted. Route of entry: Skin and/or eye contact. Inhalation. Central nervous system [/fusion_toggle][fusion_toggle title="SECTION 12: ECOLOGICAL INFORMATION" open="no"] Ecotoxicity: Dangerous for the environment if discharged into watercourses. The product contains a substance which is very toxic to aquatic organisms and which may cause long term adverse effects in the aquatic environment. Ecological information on ingredients.

WHITE SPIRIT

Ecotoxicity: Dangerous for the environment if discharged into watercourses.

12.1. Toxicity

Ecological information on ingredients.

Low Aromatic White Spirit

Acute Toxicity – Fish
LC50 96 hours > 1000 mg/l Onchorhynchus mykiss (Rainbow trout)
Substance did not cause acute toxicity to fish
EC 50, 48 Hrs, Daphnia, mg/l
>1000
Substance did not cause acute toxicity to the freshwater invertebrates

Acute Toxicity – Aquatic Plants
EC50 72 hours > 1000 mg/l Freshwater algae
Substance did not cause acute toxicity to the freshwater green algae
EC50 > 100 mg/l Activated sludge

Chronic Toxicity – Fish Early life Stage
NOEC 28 days 0.131 mg/l Onchorhynchus mykiss (Rainbow trout)
Chronic Toxicity – Aquatic Invertebrates
NOEC 28 days 0.23 mg/l Daphnia magna

WHITE SPIRIT

Dangerous for the environment if discharged into watercourses Toxic to aquatic organisms

Acute Toxicity – Fish
LC50 96 hours ~ 10 – 30 mg/l Onchorhynchus mykiss (Rainbow trout)

Acute Toxicity – Aquatic Invertebrates
EC50 48 hours 10 – 22 mg/l Daphnia magna

Acute Toxicity – Aquatic Plants
EC50 72 hours 4.6 – 10 mg/l Scenedesmus subspicatus
EC50 48 hours 43.98 mg/l Activated sludge

Chronic Toxicity – Aquatic Invertebrates
NOEC 21 days < 0.28 mg/l Daphnia magna

12.2. Persistence and degradability

Degradability: The product is not expected to be biodegradable.

Ecological information on ingredients.

Low Aromatic White Spirit

Degradability: The product is easily biodegradable.
Oxidises rapidly by photo-chemical reactions in air
Biodegradation: Degradation (80%) 28 days
Test – 301F Ready Biodegradability – Manometric Respiratory Test

WHITE SPIRIT

Degradability: The product is easily biodegradable.
Photo transformation: Scientifically unjustified.
Stability (Hydrolysis): Scientifically unjustified.
Biodegradation: Degradation (75%) 28 days
The substance is readily biodegradable.

12.3. Bioaccumulative potential

Bioaccumulative potential: The product contains potentially bioaccumulating substances.

Ecological information on ingredients.

Low Aromatic White Spirit

Bioaccumulative potential: The product contains potentially bioaccumulating substances.

Partition coefficient: 5 – 6.7

WHITE SPIRIT

Bioaccumulation factor: Scientifically unjustified.

Substance is a hydrocarbon UVCB. Standard tests for this endpoint are intended for single substances and are not appropriate for this complex substance.

Partition coefficient: Technically not feasible.

12.4. Mobility in soil

Mobility: The product contains volatile organic compounds (VOC) which will evaporate easily from all surfaces.

Ecological information on ingredients.

Low Aromatic White Spirit

Mobility: The product contains volatile organic compounds (VOC) which will evaporate easily from all surfaces. Readily absorbed into soil.

Adsorption/Desorption Coefficient: Not available.

Surface tension: 24.5 mN/m 20 °C

WHITE SPIRIT

Adsorption/Desorption Coefficient: Scientifically unjustified.

Henry’s Law Constant: Scientifically unjustified.

Volatilisation is dependent on Henry’s Law constant (HLC) which is not applicable to complex substances.

Surface tension: 24 – 27 mN/m 25 °C

12.5. Results of PBT and vPvB assessment

Ecological information on ingredients.

Low Aromatic White Spirit

Not Classified as PBT/vPvB by current EU criteria.

WHITE SPIRIT

Not Classified as PBT/vPvB by current EU criteria.

12.6. Other adverse effects

The product contains volatile, organic compounds which have a photochemical ozone creation potential.

Ecological information on ingredients.

Low Aromatic White Spirit

Not known.

WHITE SPIRIT

This substance may contribute to ozone formation in the near surface atmosphere. However, the photochemical formation of ozone depends on a complex interaction of other atmospheric pollutant sources and environmental conditions. Therefore, the contribution of this substance to ozone formation is outside the scope of this substance assessment and is more appropriately addressed via EU air quality directives.

General information: Do not allow to enter drains, sewers or watercourses.

13.1. Waste treatment methods

Dispose of waste and residues in accordance with local authority requirements.

Waste Class: When this coating, in its liquid state, as supplied, becomes a waste, it is categorised as hazardous waste, with code 08 01 11* (SOLVENT BASED LIQUID WASTE). Part-used containers, not drained and/or rigorously scraped out and containing dried residues of the supplied coating, are categorised as hazardous waste, with code 08 01 11* (SOLVENT BASED LIQUID WASTE). If mixed with other wastes, the above waste code may not be applicable. Used containers, drained and/or rigorously scraped out and containing dry residues of the supplied coating, are categorised as non-hazardous waste, with code 15 01 02 (plastic packaging) or 15 01 04 (metal packaging).

General: This product is packed in accordance with the Limited Quantity Provisions of CDGCPL2, ADR and IMDG.

14.1. UN number

UN No. (ADR/RID/ADN) 1263
UN No. (IMDG) 1263
UN No. (ICAO) 1263

14.2. UN proper shipping name

Proper Shipping Name Contains Zinc Phosphate, Class 9, PGIII & Solvent Naphtha (Petroleum), Class 3, PG III, (38 °C), MARINE POLLUTANTS

Proper Shipping Name PAINT

14.3. Transport hazard class(es)

ADR/RID/ADN Class 1263
ADR/RID/ADN Class Class 3: Flammable liquids.
IMDG Class 3
ICAO Class/Division 3

Transport Labels

14.4. Packing group

ADR/RID/ADN Packing group III
IMDG Packing group III
ICAO Packing group III

14.5. Environmental hazards

Environmentally Hazardous Substance/Marine Pollutant

14.6. Special precautions for user

EMS F-E, S-E
Tunnel Restriction Code (D/E)

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

Not applicable.

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

UK Regulatory References

The Control of Substances Hazardous to Health Regulations 2002 (S.I 2002 No. 2677) with amendments.

Statutory Instruments

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). Control of Substances Hazardous to Health.

Approved Code Of Practice

Safety Data Sheets for Substances and Preparations. Classification and Labelling of Substances and Preparations Dangerous for Supply.

Dangerous Substances and Explosive Atmospheres Regulations 2002 [L138]

Guidance Notes

Workplace Exposure Limits EH40. CHIP for everyone HSG(108).

EU Legislation

Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments.

National Regulations

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2002. No. 1689.

15.2. Chemical Safety Assessment

No chemical safety assessment has been carried out.

Revision Comments

Issued in new format for Reach compliance in accordance with EC 1272/2008 Issued in accordance with Annex II to REACH, as amended

by Commission Regulation (EU) No. 453/2010 Update for CLP labelling.

Issued By Technical Dept. (P.E.)

Revision Date 26/01/2015

Revision 8

Supersedes date 10/06/2014

SDS No. 10594

Safety Data Sheet Status Approved.

Date Date Printed________________

Signature Initials__________________

Risk Phrases In Full

R10 Flammable.

R20/21 Harmful by inhalation and in contact with skin.

R65 Harmful: may cause lung damage if swallowed.

R36/37/38 Irritating to eyes, respiratory system and skin.

R37 Irritating to respiratory system.

R43 May cause sensitisation by skin contact.

NC Not classified.

R63 Possible risk of harm to the unborn child.

R66 Repeated exposure may cause skin dryness or cracking.

R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

R67 Vapours may cause drowsiness and dizziness.

R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Hazard Statements In Full

H372 Causes damage to organs <> through prolonged or repeated exposure if inhaled.

H319 Causes serious eye irritation.

H315 Causes skin irritation.

H226 Flammable liquid and vapour.

H332 Harmful if inhaled.

H312 Harmful in contact with skin.

H304 May be fatal if swallowed and enters airways.

H317 May cause an allergic skin reaction.

H373 May cause damage to organs <> through prolonged or repeated exposure if inhaled.

H336 May cause drowsiness or dizziness.

H335 May cause respiratory irritation.

EUH066 Repeated exposure may cause skin dryness or cracking.

H361d Suspected of damaging the unborn child.

H411 Toxic to aquatic life with long lasting effects.

H410 Very toxic to aquatic life with long lasting effects.

H400 Very toxic to aquatic life.

Disclaimer

This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company’s knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user’s responsibility to satisfy himself as to the suitability of such information for his own particular use.

1.1. Product identifier

Product name TH/P201 – HIGH BUILD METAL PRIMER – RED
Product No. TH/P201/24

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses Paint.

1.3. Details of the supplier of the safety data sheet

Supplier THERMOGUARD UK LTD
Kirkby Street
Hull
HU2 0BE
+44(0)1142 768008
+44(0)1624 825115
sales@thermoguard.co.uk
Contact Person Sales Department – 08.00 – 17.00 hrs Mon – Fri. as above

1.4. Emergency telephone number

+44 (0) 1482 320194 (08.30 – 16.30 hrs Mon – Thurs, 08.30 – 15.00 hrs Fri)

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)
Physical and Chemical Hazards Flam. Liq. 3 – H226
Human health EUH066;STOT SE 3 – H336
Environment Aquatic Acute 1 – H400;Aquatic Chronic 1 – H410
Classification (1999/45/EEC) N;R50/53. R10, R66, R67.

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

2.2. Label elements

Label In Accordance With (EC) No. 1272/2008

 

Signal Word: Warning

Hazard Statements

H226 Flammable liquid and vapour.

H336 May cause drowsiness or dizziness.

H410 Very toxic to aquatic life with long lasting effects.

Precautionary Statements

P102 Keep out of reach of children.

P101 If medical advice is needed, have product container or label at hand.

P271 Use only outdoors or in a well-ventilated area.

P273 Avoid release to the environment.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P501A Dispose of contents/container to special waste collection point

Supplementary Precautionary Statements

P210 Keep away from heat/sparks/open flames/hot surfaces. – No smoking.

P233 Keep container tightly closed.

P240 Ground/bond container and receiving equipment.

P241 Use explosion-proof electrical equipment.

P242 Use only non-sparking tools.

P243 Take precautionary measures against static discharge.

P261 Avoid breathing vapour/spray.

P370+378 In case of fire: Use foam, carbon dioxide, dry powder or water fog for extinction.

P303+361+353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.

P304+340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P312 Call a POISON CENTER or doctor/physician if you feel unwell.

P391 Collect spillage.

P403+233 Store in a well-ventilated place. Keep container tightly closed.

P403+235 Store in a well-ventilated place. Keep cool.

P405 Store locked up.

Supplemental label information

EUH066 Repeated exposure may cause skin dryness or cracking.

EUH208 Contains 2-BUTANONE OXIME,Cobalt containing polymer. May produce an allergic reaction.

2.3. Other hazards

3.2. Mixtures

WHITE SPIRIT 10-30%
CAS-No.:
EC No.: 919-446-0
Classification (67/548/EEC):
Xn;R65.
N;R51/53.
R10,R66,R67.
Classification (EC 1272/2008):
Flam. Liq. 3 – H226
EUH066
STOT SE 3 – H336
STOT RE 1 – H372
Asp. Tox. 1 – H304
Aquatic Chronic 2 – H411
Registration Number: 01-2119458049-33-XXXX

Calcium Carbonate 10-30%
CAS-No.: 1317-65-3
EC No.: 215-279-6
Classification (67/548/EEC): Not classified.
Classification (EC 1272/2008): Not classified.

Red Iron Oxide 5-10%
CAS-No.: 1309-37-1
EC No.:
Classification (67/548/EEC): Not classified.
Classification (EC 1272/2008): Not classified.

Barium Sulphate 5-10%
CAS-No.: 7727-43-7
EC No.: 231-784-4
Classification (67/548/EEC): Not classified.
Classification (EC 1272/2008): Not classified.
Registration Number: 01-2119491274-35-0001

TRIZINC BIS(ORTHOPHOSPHATE) 1-5%
CAS-No.: 7779-90-0
EC No.: 231-944-3
Classification (67/548/EEC): N;R50/53
Classification (EC 1272/2008):
Aquatic Acute 1 – H400
Aquatic Chronic 1 – H410
Registration Number: 01-2119485044-40-0000

Low Aromatic White Spirit 1-5%
CAS-No.:
EC No.: 919-857-5
Classification (67/548/EEC):
Xn;R65.
R10,R66,R67.
Classification (EC 1272/2008):
Flam. Liq. 3 – H226
EUH066
STOT SE 3 – H336
Asp. Tox. 1 – H304
Registration Number: 01-2119463258-33-XXXX

Cobalt containing polymer <1% CAS-No.: EC No.: Classification (67/548/EEC): R43. Classification (EC 1272/2008): Skin Sens. 1 - H317 Low Aromatic White Spirit <1% CAS-No.: 64742-48-9 EC No.: 265-150-3 Classification (67/548/EEC): Xn;R65. R10. Classification (EC 1272/2008): Flam. Liq. 3 - H226 Asp. Tox. 1 - H304 Registration Number: 01-2119457273-39 Zinc Oxide <1% CAS-No.: 1314-13-2 EC No.: 215-222-5 Classification (67/548/EEC): N;R50/53. Classification (EC 1272/2008): Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410 Registration Number: 01-2119463881-32 2-BUTANONE OXIME <1% CAS-No.: 96-29-7 EC No.: 202-496-6 Classification (67/548/EEC): Carc. Cat. 3;R40 Xn;R21 R43 Xi;R41 Classification (EC 1272/2008): Acute Tox. 4 - H312 Eye Dam. 1 - H318 Skin Sens. 1 - H317 Carc. 2 - H351 Registration Number: 01-2119539477-28 2-METHYLPENTANE-2,4-DIOL <0.1% CAS-No.: 107-41-5 EC No.: 203-489-0 Classification (67/548/EEC): Xi;R36/38 Classification (EC 1272/2008): Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 ZIRCONIUM SALT, 2-ETHYLHEXANOIC ACID <0.1% CAS-No.: 22464-99-9 EC No.: 245-018-1 Classification (67/548/EEC): Repr. Cat. 3;R63. Classification (EC 1272/2008): Repr. 2 - H361d Registration Number: 01-2119979088-21-0002 XYLENE, MIXED ISOMERS <0.1% CAS-No.: 1330-20-7 EC No.: 215-535-7 Classification (67/548/EEC): Xn;R20/21,R65. Xi;R36/37/38. R10. Classification (EC 1272/2008): Flam. Liq. 3 - H226 Acute Tox. 4 - H312 Acute Tox. 4 - H332 Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 STOT SE 3 - H335 STOT RE 2 - H373 Asp. Tox. 1 - H304 Registration Number: 01-2119488216-32-xxxx ZIRCONIUM PROPIONATE <0.1% CAS-No.: 84057-80-7 EC No.: 281-897-8 Classification (67/548/EEC): Not classified. Classification (EC 1272/2008): Not classified. Registration Number: 01-2119978305-30-0000 2,6-Di-tert-butyl-p-cresol <0.1% CAS-No.: 128-37-0 EC No.: 204-881-4 Classification (67/548/EEC): N;R50/53. Classification (EC 1272/2008): Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410 Registration Number: 01-2119565113-46-xxxx The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. [/fusion_toggle][fusion_toggle title="SECTION 4: FIRST AID MEASURES" open="no"]

4.1. Description of first aid measures

General information: General first aid, rest, warmth and fresh air. Do not give victim anything to drink if they are unconscious.

Inhalation: Remove victim immediately from source of exposure. Provide rest, warmth and fresh air. Get medical attention if any discomfort continues. Place unconscious person on the side in the recovery position and ensure breathing can take place.

Ingestion: DO NOT induce vomiting. Get medical attention immediately. Provide fresh air, warmth and rest, preferably in comfortable upright sitting position.

Skin contact: Remove affected person from source of contamination. Remove contaminated clothing immediately and wash skin with soap and water.

Eye contact: Make sure to remove any contact lenses from the eyes before rinsing. Continue to rinse for at least 15 minutes and get medical attention.

4.2. Most important symptoms and effects, both acute and delayed

General information: If adverse symptoms develop as described the casualty should be transferred to hospital as soon as possible.

4.3. Indication of any immediate medical attention and special treatment needed

No specific first aid measures noted.

5.1. Extinguishing media

Extinguishing media: Extinguish with foam, carbon dioxide, dry powder or water fog. Do not use water jet as an extinguisher, as this will spread the fire.

5.2. Special hazards arising from the substance or mixture

Unusual Fire & Explosion Hazards: FLAMMABLE. Solvent vapours may form explosive mixtures with air.

Specific hazards: When heated and in case of fire, harmful vapours/gases may be formed.

5.3. Advice for firefighters

Special Fire Fighting Procedures: Be aware of danger for fire to re-start. Cool containers exposed to flames with water until well after the fire is out. Do not allow runoff to sewer, waterway or ground.

Protective equipment for fire-fighters: Selection of respiratory protection for fire fighting: follow the general fire precautions indicated in the workplace.

6.1. Personal precautions, protective equipment and emergency procedures

Avoid inhalation of vapours and contact with skin and eyes. Provide adequate ventilation. Do not smoke, use open fire or other sources of ignition. Ensure suitable personal protection (including respiratory protection) during removal of spillages in a confined area.

6.2. Environmental precautions

Do not discharge into drains, water courses or onto the ground. Contain spillages with sand, earth or any suitable adsorbent material. Spillages or uncontrolled discharges into watercourses must be IMMEDIATELY alerted to the Environmental Agency or other appropriate regulatory body.

6.3. Methods and material for containment and cleaning up

Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate. Should be prevented from entering drains. Absorb in vermiculite, dry sand or earth and place into containers. Collect spillage in containers, seal securely and deliver for disposal according to local regulations.

6.4. Reference to other sections

For personal protection, see section 8.

7.1. Precautions for safe handling

Observe occupational exposure limits and minimise the risk of inhalation of vapours and mist. Keep away from heat, sparks and open flame. Avoid spilling, skin and eye contact. Ventilate well, avoid breathing vapours. Use approved respirator if air contamination is above accepted level. Do not eat, drink or smoke when using the product. The Manual Handling Operations Regulations may apply to the handling of containers of this product. To assist employers, the following method of calculating the weight for any pack size is given. Take the pack size volume in litres and multiply this figure by the specific gravity value given in section 9. This will give the net weight of the coating in kilograms. Allowance will then have to be made for the immediate packaging to give an approximate gross weight.

7.2. Conditions for safe storage, including any incompatibilities

Store in closed original container at temperatures between 5°C and 25°C. Keep away from heat, sparks and open flame. Keep containers tightly closed. Keep upright. Store separated from: Oxidising material. Alkalis. Acids.

Storage Class: Flammable liquid storage. The storage and use of this product is subject to the Dangerous Substances and Explosive Atmospheres Regulations (DSEAR). The requirements are given in the HSE Approved Code of Practice and Guidance, Storage od Danderous Substances: DSEAR. Up to 250 litres of liquids with a flashpoint above 32C but below 55C may be kept in a workroom provided they are kept in closed containers in a marked, fire-resisting cupboard or bin. Larger quantities must be kept in a separate , marked storeroom conforming to the structural requirements contained in the HSE guidance note Storage of Flammable Liquids in Containers.

7.3. Specific end use(s)

The identified uses for this product are detailed in Section 1.2.

Usage Description: Ensure that waste and contaminated materials are collected and removed from the work area as soon as possible in a suitably labelled container.

8.1. Control parameters

WEL = Workplace Exposure Limit.
Sk = Can be absorbed through skin.

8.2. Exposure controls

Protective equipment: Goggles & Gloves

Engineering measures: Provide adequate ventilation, including appropriate local extraction, to ensure that the defined occupational exposure limit is not exceeded.

Respiratory equipment: No specific recommendation made, but respiratory protection must be used if the general level exceeds the recommended occupational exposure limit.

Hand protection: Use suitable protective gloves if risk of skin contact. The most suitable glove must be chosen in consultation with the gloves supplier, who can inform about the breakthrough time of the glove material. Barrier cream applied before work may make it easier to clean the skin after exposure, but does not prevent absorption through the skin.

Eye protection: Wear splash-proof eye goggles to prevent any possibility of eye contact.

Other Protection: Wear appropriate clothing to prevent reasonably probable skin contact.

Hygiene measures: No specific hygiene procedures noted, but good personal hygiene practices are always advisable, especially when working with chemicals.

9.1. Information on basic physical and chemical properties

Appearance: Viscous Coloured liquid.
Colour: Red.
Solubility: Insoluble in water
Relative density: @ 20 1.3 approx.
Vapour density (air=1): heavier than air
Viscosity: 3.5 (Rotothinner) Ps @ 25
Flash point (°C): 38 approx. CC (Closed cup).
Flammability Limit – Lower(%): 0.8

9.2. Other information

Volatile Organic Compound (VOC): 430 g/litre

10.1. Reactivity

There are no known reactivity hazards associated with this product.

10.2. Chemical stability

Stable under normal temperature conditions and recommended use.

10.3. Possibility of hazardous reactions

Not determined.

10.4. Conditions to avoid

Avoid contact with water. Avoid heat, flames and other sources of ignition. Avoid contact with acids and oxidising substances. Exothermic reaction with amines and alcohols; reacts slowly with water forming CO2, in closed containers risk of bursting owing to increase of pressure.

10.5. Incompatible materials

Materials To Avoid: Strong alkalis. Strong acids. Strong oxidising substances.

10.6. Hazardous decomposition products

Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours.

11.1. Information on toxicological effects

Inhalation: Vapour from this chemical can be hazardous when inhaled. Vapour may irritate respiratory system or lungs.

Ingestion: Liquid irritates mucous membranes and may cause abdominal pain if swallowed.

Skin contact: Acts as a defatting agent on skin. May cause cracking of skin, and eczema. Prolonged or repeated exposure may cause severe irritation.

Eye contact: May cause temporary eye irritation.

Health Warnings: This product has low toxicity. Only large volumes may have adverse impact on human health.

Route of entry: Inhalation. Skin absorption. Ingestion. Skin and/or eye contact.

Medical Considerations: Skin disorders and allergies. Avoid vomiting and normal rinse of stomach because of risk of aspiration.

Toxicological information on ingredients.

TRIZINC BIS(ORTHOPHOSPHATE) (CAS: 7779-90-0)

Toxic Dose 1 – LD 50 5000 mg/kg (oral rat)
Toxic Dose 2 – LD 50 522 mg/kg (ipr-mouse)
Toxic Conc. – LC 50 >5.7 mg/l/4h (inh-rat)

Acute toxicity:
Not irritating

Skin Corrosion/Irritation:
Not irritating.

Serious eye damage/irritation:
Not Irritating.

Respiratory or skin sensitisation:
Not sensitising.
Not Sensitising.

Germ cell mutagenicity:
Does not contain any substances known to be mutagenic.

Carcinogenicity:
This substance has no evidence of carcinogenic properties.

Reproductive Toxicity:
This substance has no evidence of toxicity to reproduction.

Specific target organ toxicity – single exposure:
Not classified as a specific target organ toxicant after a single exposure.

Specific target organ toxicity – repeated exposure:
Not classified as a specific target organ toxicant after repeated exposure.

Aspiration hazard:
General information
No specific health warnings noted.

Low Aromatic White Spirit

Acute toxicity:
Acute Toxicity (Oral LD50) > 5000 mg/kg Rat
Acute Toxicity (Dermal LD50) > 5000 mg/kg Rabbit
Acute Toxicity (Inhalation LC50) > 5 mg/l (vapours) Rat 4 hours

Skin Corrosion/Irritation:
Erythema\eschar score: Very slight erythema -barely perceptible (1). Well defined erythema (2).
Oedema score: No oedema (0).
Slightly irritating.

Serious eye damage/irritation:
Not Irritating.

Respiratory or skin sensitisation:
Not sensitising.
Skin sensitisation
Guinea pig maximization test (GPMT): Guinea Pig
Not Sensitising.
Germ cell mutagenicity:
Genotoxicity – In Vitro

Chromosome aberration:
Negative.
This substance has no evidence of mutagenic properties.

Carcinogenicity:
Inhalation. Rat
This substance has no evidence of carcinogenic properties. Does not contain any substances known to be carcinogenic.

Reproductive Toxicity:
Reproductive Toxicity – Fertility
Fertility: Inhalation. Rat
This substance has no evidence of toxicity to reproduction.
Reproductive Toxicity – Development
Developmental toxicity: Inhalation. Rat
This substance has no evidence of toxicity to reproduction.

Specific target organ toxicity – repeated exposure:
STOT – Repeated exposure
Not available.

Aspiration hazard:

Viscosity: Kinematic viscosity <= 20.5 mm2/s. Inhalation: Vapours may cause drowsiness and dizziness. Central nervous system depression. Ingestion: Harmful: danger of serious damage to health by prolonged exposure if swallowed. Skin contact: Acts as a defatting agent on skin. May cause cracking of skin, and eczema. Eye contact: No specific health warnings noted. Route of entry: Inhalation. Ingestion.

WHITE SPIRIT

Other Health Effects: This substance has no evidence of carcinogenic properties.

Acute toxicity:
Acute Toxicity (Oral LD50)
> 15000 mg/kg Rat
Conclusive data but not sufficient for classification.
Acute Toxicity (Dermal LD50)
~ 3400 mg/kg Rabbit
Conclusive data but not sufficient for classification.
Acute Toxicity (Inhalation LC50)
> 13.1 mg/l (vapours) Rat 4 hours
Conclusive data but not sufficient for classification.
ATE (Inhalation)
13.1 mg/l (vapours)

Skin Corrosion/Irritation:
Erythema\eschar score: Very slight erythema -barely perceptible (1).
Oedema score: Very slight oedema -barely perceptible (1).
Not irritating.
Not irritating. Non Corrosive to skin.

Serious eye damage/irritation:
Not Irritating.

Respiratory or skin sensitisation:
Respiratory sensitisation
Inconclusive data.
There is evidence that the material can lead to respiratory hypersensitivity.
Skin sensitisation
Guinea pig maximization test (GPMT): Guinea Pig
Not Sensitising.

Germ cell mutagenicity:
Genotoxicity – In Vitro
Bacterial Reverse Mutation Test
Negative.
This substance has no evidence of mutagenic properties.
Genotoxicity – In Vivo
Chromosome aberration:
Negative.

Carcinogenicity:
Carcinogenicity
NOAEL 300 mg/kg Oral Rat
NOAEL >2200 mg/m3 Inhalation. Rat

Reproductive Toxicity:
Reproductive Toxicity – Fertility
One-generation study: NOAEL >3000 mg/kg/day Oral Rat P
Reproductive Toxicity – Development
Developmental toxicity: NOAEC >300 ppm Inhalation. Rat

Specific target organ toxicity – single exposure:
Target Organs: Central nervous system
Central nervous system depression including narcotic effects such as drowsiness, narcosis, reduced alertness, loss of reflexes, lack of coordination and vertigo.

Specific target organ toxicity – repeated exposure:
STOT – Repeated exposure
NOAEL 1056 mg/kg Oral Rat
Target Organs: Central nervous system

Aspiration hazard:
Viscosity: Kinematic viscosity <= 20.5 mm2/s. Inhalation: Vapours may cause drowsiness and dizziness. Ingestion: Harmful: may cause lung damage if swallowed. May cause stomach pain or vomiting. Skin contact: May cause defatting of the skin, but is not an irritant. Not a skin sensitiser. Eye contact: No specific health warnings noted. Route of entry: Skin and/or eye contact. Inhalation. Central nervous system [/fusion_toggle][fusion_toggle title="SECTION 12: ECOLOGICAL INFORMATION" open="no"] Ecotoxicity: Dangerous for the environment if discharged into watercourses. The product contains a substance which is very toxic to aquatic organisms and which may cause long term adverse effects in the aquatic environment. Ecological information on ingredients.

WHITE SPIRIT

Ecotoxicity: Dangerous for the environment if discharged into watercourses.

12.1. Toxicity

Ecological information on ingredients.

TRIZINC BIS(ORTHOPHOSPHATE) (CAS: 7779-90-0)

LC 50, 96 Hrs, Fish mg/l
Oncorhynchus mykiss 0.14 – 0.26 Zn2+
EC 50, 48 Hrs, Daphnia, mg/l
Daphnia magna 0.04 – 0.86 Zn2+
IC 50, 72 Hrs, Algae, mg/l
Desmodesmus subspicatus <0.3 EC50 72 hours 0.136 - 0.15 Zn2+ mg/l Selenastrum capricornutum

Low Aromatic White Spirit

Acute Toxicity – Fish
LC50 96 hours > 1000 mg/l Onchorhynchus mykiss (Rainbow trout)
Substance did not cause acute toxicity to fish
EC 50, 48 Hrs, Daphnia, mg/l
>1000
Substance did not cause acute toxicity to the freshwater invertebrates

Acute Toxicity – Aquatic Plants
EC50 72 hours > 1000 mg/l Freshwater algae
Substance did not cause acute toxicity to the freshwater green algae
EC50 > 100 mg/l Activated sludge

Chronic Toxicity – Fish Early life Stage
NOEC 28 days 0.131 mg/l Onchorhynchus mykiss (Rainbow trout)

Chronic Toxicity – Aquatic Invertebrates
NOEC 28 days 0.23 mg/l Daphnia magna

WHITE SPIRIT

Dangerous for the environment if discharged into watercourses Toxic to aquatic organisms

Acute Toxicity – Fish
LC50 96 hours ~ 10 – 30 mg/l Onchorhynchus mykiss (Rainbow trout)

Acute Toxicity – Aquatic Invertebrates
EC50 48 hours 10 – 22 mg/l Daphnia magna

Acute Toxicity – Aquatic Plants
EC50 72 hours 4.6 – 10 mg/l Scenedesmus subspicatus
EC50 48 hours 43.98 mg/l Activated sludge

Chronic Toxicity – Aquatic Invertebrates
NOEC 21 days < 0.28 mg/l Daphnia magna

12.2. Persistence and degradability

Degradability: The product is not expected to be biodegradable.

Ecological information on ingredients.

Low Aromatic White Spirit

Degradability: The product is easily biodegradable.
Oxidises rapidly by photo-chemical reactions in air
Biodegradation: Degradation (80%) 28 days
Test – 301F Ready Biodegradability – Manometric Respiratory Test

WHITE SPIRIT

Degradability: The product is easily biodegradable.
Photo transformation: Scientifically unjustified.
Stability (Hydrolysis): Scientifically unjustified.
Biodegradation: Degradation (75%) 28 days
The substance is readily biodegradable.

12.3. Bioaccumulative potential

Bioaccumulative potential: The product contains potentially bioaccumulating substances.

Ecological information on ingredients.

TRIZINC BIS(ORTHOPHOSPHATE) (CAS: 7779-90-0)

Bioaccumulative potential: The product is not bioaccumulating.

Low Aromatic White Spirit

Bioaccumulative potential: The product contains potentially bioaccumulating substances.
Partition coefficient: 5 – 6.7

WHITE SPIRIT

Bioaccumulation factor: Scientifically unjustified.
Substance is a hydrocarbon UVCB. Standard tests for this endpoint are intended for single substances and are not appropriate for this complex substance.
Partition coefficient: Technically not feasible.

12.4. Mobility in soil

Mobility: The product contains volatile organic compounds (VOC) which will evaporate easily from all surfaces.

Ecological information on ingredients.

Low Aromatic White Spirit

Mobility: The product contains volatile organic compounds (VOC) which will evaporate easily from all surfaces. Readily absorbed into soil.
Adsorption/Desorption Coefficient: Not available.
Surface tension: 24.5 mN/m 20 °C

WHITE SPIRIT

Adsorption/Desorption Coefficient: Scientifically unjustified.
Henry’s Law Constant: Scientifically unjustified.
Volatilisation is dependent on Henry’s Law constant (HLC) which is not applicable to complex substances.
Surface tension: 24 – 27 mN/m 25 °C

12.5. Results of PBT and vPvB assessment

Ecological information on ingredients.

TRIZINC BIS(ORTHOPHOSPHATE) (CAS: 7779-90-0)

Not Classified as PBT/vPvB by current EU criteria.

Low Aromatic White Spirit

Not Classified as PBT/vPvB by current EU criteria.

WHITE SPIRIT

Not Classified as PBT/vPvB by current EU criteria.

12.6. Other adverse effects

The product contains volatile, organic compounds which have a photochemical ozone creation potential.

Ecological information on ingredients.

TRIZINC BIS(ORTHOPHOSPHATE) (CAS: 7779-90-0)

Not available.

Low Aromatic White Spirit

Not known.

WHITE SPIRIT

This substance may contribute to ozone formation in the near surface atmosphere. However, the photochemical formation of ozone depends on a complex interaction of other atmospheric pollutant sources and environmental conditions. Therefore, the contribution of this substance to ozone formation is outside the scope of this substance assessment and is more appropriately addressed via EU air quality directives.

General information: Do not allow to enter drains, sewers or watercourses.

13.1. Waste treatment methods

Dispose of waste and residues in accordance with local authority requirements.

Waste Class: When this coating, in its liquid state, as supplied, becomes a waste, it is categorised as hazardous waste, with code 08 01 11* (SOLVENT BASED LIQUID WASTE). Part-used containers, not drained and/or rigorously scraped out and containing dried residues of the supplied coating, are categorised as hazardous waste, with code 08 01 11* (SOLVENT BASED LIQUID WASTE). If mixed with other wastes, the above waste code may not be applicable. Used containers, drained and/or rigorously scraped out and containing dry residues of the supplied coating, are categorised as non-hazardous waste, with code 15 01 02 (plastic packaging) or 15 01 04 (metal packaging).

General: This product is packed in accordance with the Limited Quantity Provisions of CDGCPL2, ADR and IMDG.

14.1. UN number

UN No. (ADR/RID/ADN) 1263
UN No. (IMDG) 1263
UN No. (ICAO) 1263

14.2. UN proper shipping name

Proper Shipping Name Contains Zinc Phosphate, Class 9, PGIII & Solvent Naphtha (Petroleum), Class 3, PG III, (38 °C), MARINE POLLUTANTS
Proper Shipping Name PAINT

14.3. Transport hazard class(es)

ADR/RID/ADN Class 1263
ADR/RID/ADN Class Class 3: Flammable liquids.
IMDG Class 3
ICAO Class/Division 3

Transport Labels

14.4. Packing group

ADR/RID/ADN Packing group III
IMDG Packing group III
ICAO Packing group III

14.5. Environmental hazards

Environmentally Hazardous Substance/Marine Pollutant

14.6. Special precautions for user

EMS F-E, S-E
Tunnel Restriction Code (D/E)

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

Not applicable.

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

UK Regulatory References

The Control of Substances Hazardous to Health Regulations 2002 (S.I 2002 No. 2677) with amendments.

Statutory Instruments

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). Control of Substances Hazardous to Health.

Approved Code Of Practice

Safety Data Sheets for Substances and Preparations. Classification and Labelling of Substances and Preparations Dangerous for Supply.

Dangerous Substances and Explosive Atmospheres Regulations 2002 [L138]

Guidance Notes

Workplace Exposure Limits EH40. CHIP for everyone HSG(108).

EU Legislation

Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments.

National Regulations

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2002. No. 1689.

15.2. Chemical Safety Assessment

No chemical safety assessment has been carried out.

Revision Comments

This is first issue. Issued in new format for Reach compliance in accordance with EC 1272/2008 Issued in accordance with Annex II to REACH, as amended by Commission Regulation (EU) No. 453/2010

Issued By Technical Dept. (P.E.)

Revision Date 30/08/2016

Revision 0

Supersedes date FIRST ISSUE

SDS No. 11810

Safety Data Sheet Status Approved.

Date Date Printed________________

Signature Initials__________________

Risk Phrases In Full

R10 Flammable.

R20/21 Harmful by inhalation and in contact with skin.

R21 Harmful in contact with skin.

R65 Harmful: may cause lung damage if swallowed.

R36/38 Irritating to eyes and skin.

R36/37/38 Irritating to eyes, respiratory system and skin.

R40 Limited evidence of a carcinogenic effect.

R43 May cause sensitisation by skin contact.

NC Not classified.

R63 Possible risk of harm to the unborn child.

R66 Repeated exposure may cause skin dryness or cracking.

R41 Risk of serious damage to eyes.

R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

R67 Vapours may cause drowsiness and dizziness.

R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Hazard Statements In Full

H372 Causes damage to organs <> through prolonged or repeated exposure if inhaled.

H318 Causes serious eye damage.

H319 Causes serious eye irritation.

H315 Causes skin irritation.

H226 Flammable liquid and vapour.

H332 Harmful if inhaled.

H312 Harmful in contact with skin.

H304 May be fatal if swallowed and enters airways.

H317 May cause an allergic skin reaction.

H373 May cause damage to organs <> through prolonged or repeated exposure if inhaled.

H336 May cause drowsiness or dizziness.

H335 May cause respiratory irritation.

EUH066 Repeated exposure may cause skin dryness or cracking.

H351 Suspected of causing cancer.

H361d Suspected of damaging the unborn child.

H411 Toxic to aquatic life with long lasting effects.

H410 Very toxic to aquatic life with long lasting effects.

H400 Very toxic to aquatic life.

Disclaimer

This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company’s knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user’s responsibility to satisfy himself as to the suitability of such information for his own particular use.

DO YOU HAVE ANY QUESTIONS?

EMAIL US

YOU MAY ALSO NEED