Project Description

VIEW WOODSTAIN CHART

Important Note:
When using Fire Varnish always ensure adequate ventilation.

Thermoguard Fire Varnish Overcoat is a part of a varnish system with the option of a clear, tinted or stained finish for Fire Protection of INTERNAL timber and timber derivative substrates.

The special water-based formula provides durable finish to internal wood.

Clear or stained finishes enhance the natural beauty of the wood while fire protecting new and previously varnished surfaces.

When exposed to fire, Thermoguard Fire Varnish expands to create an insulating barrier, protecting timber surfaces from flames, heat and oxygen and suppressing emission of deadly smoke & gasses.

  • Matt or Satin
  • Clear finish — 1 coat basecoat + 1 coat Overcoat (2nd coat for wear areas)
  • Stained Varnish finish – 1 coat basecoat + 2 coats Overcoat
  • Increased UV protection for fruitwoods – 1 coat basecoat + 2 coats Overcoat
  • NOTE – for pools, heavily or regularly washed areas see Exterior Overcoat

See Data Sheets and additional information below

AVAILABLE IN:
20 & 80 square metre packs

THERMOGUARD FIRE VARNISH

Class B s2 dO + Class O INTUMESCENT CLEAR + STAINED VARNISH

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SAFETY DATA SHEET
NG FV OVERCOAT GENERAL

Compilation date: 12/11/2014
Revision No: 1

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1.1. Product identifier

Product name TH/Q417 – WATER BASED FIRE VARNISH OVERCOAT – GLOSS

Product No. TH/Q417/27

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses Paint.

1.3. Details of the supplier of the safety data sheet

Supplier THERMOGUARD UK LTD
Kirkby Street
Hull
HU2 0BE
+44(0)1142 768008
+44(0)1624 825115
sales@thermoguard.co.uk
Contact Person Sales Department – 08.00 – 17.00 hrs Mon – Fri. as above

1.4. Emergency telephone number

+44 (0) 1142 678008 Thermoguard UK Ltd (08.00 – 17.00 hrs Mon – Fri)

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)

Physical and Chemical Hazards Not classified.

Human health Not classified.

Environment Not classified.

Classification (1999/45/EEC) Not classified.

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

2.2. Label elements

Label In Accordance With (EC) No. 1272/2008

No pictogram required.

Precautionary Statements:

P102 Keep out of reach of children.

P101 If medical advice is needed, have product container or label at hand.

P262 Do not get in eyes, on skin, or on clothing.

P271 Use only outdoors or in a well-ventilated area.

P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P337+313 If eye irritation persists: Get medical advice/attention.

P501 Dispose of contents/container in accordance with national regulations.

Supplemental label information: EUH208 Contains 2,4,7,9-TETRAMETHYLDEC-5-YNE-4,7-DIOL. May produce an allergic reaction.

2.3. Other hazards

3.2. Mixtures

2-(2-BUTOXYETHOXY)ETHANOL <1%
CAS-No.: 112-34-5
EC No.: 203-961-6
Classification (67/548/EEC): Xi;R36
Classification (EC 1272/2008): Eye Irrit. 2 – H319
Registration Number: 01-2119475104-44-0002

Mixture of branched and linear C7-C9 alkyl 3-[3-(2H-benzotrizol-2-yl)-5-(1,1-demethylethyl)-4-hydroxyphenyl]propionates <1% CAS-No.: 127519-17-9
EC No.: 407-000-3
Classification (67/548/EEC) N;R51/53.
Classification (EC 1272/2008) Aquatic Chronic 2 – H411
Registration Number: 01-0000015648-61

2,4,7,9-TETRAMETHYLDEC-5-YNE-4,7-DIOL <1%
CAS-No.: 126-86-3
EC No.: 204-809-1
Classification (67/548/EEC) Xi;R41. R43,R52/53.
Classification (EC 1272/2008) Eye Dam. 1 – H318; Skin Sens. 1 – H317; Aquatic Chronic 3 – H412.
Registration Number: 01-2119954390-39

ETHANEDIOL <1%
CAS-No.: 107-21-1
EC No.: 203-473-3
Classification (67/548/EEC) Xn;R22
Classification (EC 1272/2008) Acute Tox. 4 – H302
Registration Number: 01-2119456816-28

SODIUM HYDROXIDE <0.1%
CAS-No.: 1310-73-2
EC No.: 215-185-5
Classification (EC 1272/2008) Skin Corr. 1A – H314
Classification (67/548/EEC) C;R35

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

4.1. Description of first aid measures

General information: General first aid, rest, warmth and fresh air. Do not give victim anything to drink if they are unconscious.

Inhalation: Remove victim immediately from source of exposure. Provide rest, warmth and fresh air. Get medical attention if any discomfort continues. Place unconscious person on the side in the recovery position and ensure breathing can take place.

Ingestion: DO NOT induce vomiting. Get medical attention immediately. Provide fresh air, warmth and rest, preferably in comfortable upright sitting position.

Skin contact: Remove affected person from source of contamination. Remove contaminated clothing immediately and wash skin with soap and water.

Eye contact: Make sure to remove any contact lenses from the eyes before rinsing. Continue to rinse for at least 15 minutes and get medical attention.

4.2. Most important symptoms and effects, both acute and delayed

General information: If adverse symptoms develop as described the casualty should be transferred to hospital as soon as possible.

4.3. Indication of any immediate medical attention and special treatment needed

No specific first aid measures noted.

5.1. Extinguishing media

Extinguishing media: Extinguish with foam, carbon dioxide, dry powder or water fog. Do not use water jet as an extinguisher, as this will spread the fire.

5.2. Special hazards arising from the substance or mixture

Specific hazards: The product is non-combustible. If heated, corrosive and toxic vapours/gases may be formed.

5.3. Advice for firefighters

Special Fire Fighting Procedures: Avoid breathing fire vapours. Do not allow runoff to sewer, waterway or ground. Cool containers exposed to flames with water until well after the fire is out.

Protective equipment for fire-fighters: Selection of respiratory protection for fire fighting: follow the general fire precautions indicated in the workplace.

6.1. Personal precautions, protective equipment and emergency procedures

Avoid inhalation of vapours and contact with skin and eyes. Provide adequate ventilation. Wear protective clothing as described in Section 8 of this safety data sheet.

6.2. Environmental precautions

Avoid discharge into drains, water courses or onto the ground. Contain spillages with sand, earth or any suitable adsorbent material. Spillages or uncontrolled discharges into watercourses must be IMMEDIATELY alerted to the Environmental Agency or other appropriate regulatory body.

6.3. Methods and material for containment and cleaning up

Should be prevented from entering drains. Absorb in vermiculite, dry sand or earth and place into containers. Collect spillage in containers, seal securely and deliver for disposal according to local regulations.

6.4. Reference to other sections

For personal protection, see section 8.

7.1. Precautions for safe handling

Keep away from heat, sparks and open flame. Avoid spilling, skin and eye contact. Avoid inhalation of vapours and spray mists. Do not eat, drink or smoke when using the product. Good personal hygiene is necessary. Wash hands and contaminated areas with water and soap before leaving the work site. The Manual Handling Operations Regulations may apply to the handling of containers of this product. To assist employers, the following method of calculating the weight for any pack size is given. Take the pack size volume in litres and multiply this figure by the specific gravity value given in section 9. This will give the net weight of the coating in kilograms. Allowance will then have to be made for the immediate packaging to give an approximate gross weight.

7.2. Conditions for safe storage, including any incompatibilities

Store in closed original container at temperatures between 5°C and 25°C. Keep away from heat, sparks and open flame. Protect from freezing and direct sunlight. Keep containers tightly closed. Keep upright. Store separated from: Oxidising material. Alkalis. Acids.

7.3. Specific end use(s)

The identified uses for this product are detailed in Section 1.2.

Usage Description: Ensure that waste and contaminated materials are collected and removed from the work area as soon as possible in a suitably labelled container.

8.1. Control parameters

WEL = Workplace Exposure Limit.

8.2. Exposure controls

Protective equipment: Goggles & Gloves

Engineering measures: Provide adequate ventilation. Observe Occupational Exposure Limits and minimise the risk of inhalation of vapours.

Respiratory equipment: No specific recommendation made, but respiratory protection may still be required under exceptional circumstances when excessive air contamination exists.

Hand protection: Use suitable protective gloves if risk of skin contact. The most suitable glove must be chosen in consultation with the gloves supplier, who can inform about the breakthrough time of the glove material. Barrier cream applied before work may make it easier to clean the skin after exposure, but does not prevent absorption through the skin.

Eye protection: Wear approved, tight fitting safety glasses where splashing is probable.

Other Protection: Wear appropriate clothing to prevent reasonably probable skin contact.

Hygiene measures: No specific hygiene procedures noted, but good personal hygiene practices are always advisable, especially when working with chemicals.

9.1. Information on basic physical and chemical properties

Appearance Creamy liquid.

Colour White / off-white.

Solubility Miscible with water

Initial boiling point and boiling range (°C) >100 760 mm Hg

Relative density 1.17 – 1.19 @ 20 °C

pH-Value, Conc. Solution 4 – 5

Viscosity 1.6 – 1.8 (ICI Rotothinner) Ps @ 25 °C

9.2. Other information

Volatile By Vol. (%) 65

Volatile Organic Compound (VOC)

10.1. Reactivity

No specific reactivity hazards associated with this product.

10.2. Chemical stability

Stable under normal temperature conditions and recommended use.

10.3. Possibility of hazardous reactions

Not determined.

10.4. Conditions to avoid

Avoid heat, flames and other sources of ignition. Avoid contact with acids and oxidising substances.

10.5. Incompatible materials

Materials To Avoid: Strong alkalis. Strong acids. Strong oxidising substances.

10.6. Hazardous decomposition products

Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours.

11.1. Information on toxicological effects

Toxicological information: No data recorded.

General information: No specific health warnings noted.

Inhalation: No specific health warnings noted.

Ingestion:No harmful effects expected in amounts likely to be ingested by accident.

Skin contact: Prolonged contact may cause dryness of the skin.

Eye contact: May cause temporary eye irritation.

Health Warnings: This product has low toxicity. Only large volumes may have adverse impact on human health.

Route of entry: Skin absorption. Ingestion. Skin and/or eye contact.

Medical Considerations: Skin disorders and allergies.

Ecotoxicity

There are no data on the ecotoxicity of this product.

12.1. Toxicity

12.2. Persistence and degradability

Degradability: The product is expected to be biodegradable.

12.3. Bioaccumulative potential

Bioaccumulative potential: No data available on bioaccumulation.

12.4. Mobility in soil

Mobility: The product contains substances, which are water soluble and may spread in water systems.

12.5. Results of PBT and vPvB assessment

12.6. Other adverse effects

Not determined.

General information: Do not allow to enter drains, sewers or watercourses. Waste to be treated as controlled waste. Disposal to licensed waste disposal site in accordance with local Waste Disposal Authority.

13.1. Waste treatment methods

Do not allow runoff to sewer, waterway or ground.

Waste Class: When this coating, in its liquid state, as supplied, becomes a waste, it is categorised as non-hazardous waste, with code 08 01 12 (WATER BASED LIQUID WASTE). Part used containers, not drained and/or rigorously scraped out and containing dry residues of the supplied coating, are categorised as non-hazardous waste, with code 08 01 12 (WATER BASED LIQUID WASTE). If mixed with other wastes, the above waste code may not be applicable. Used containers, drained and/or rigorously scraped out and containing dry residues of the supplied coating, are categorised as non-hazardous waste, with code 15 01 02 (plastic packaging) or 15 01 04 (metal packaging).

General: The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA, ADR/RID).

14.1. UN number

Not applicable.

14.2. UN proper shipping name

Not applicable.

14.3. Transport hazard class(es)

Not applicable.

14.4. Packing group

Not applicable.

14.5. Environmental hazards

Environmentally Hazardous Substance/Marine Pollutant: No.

14.6. Special precautions for user

No information required.

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

Not applicable.

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

UK Regulatory References

The Control of Substances Hazardous to Health Regulations 2002 (S.I 2002 No. 2677) with amendments.

Statutory Instruments

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). Control of Substances Hazardous to Health.

Approved Code Of Practice

Safety Data Sheets for Substances and Preparations. Classification and Labelling of Substances and Preparations Dangerous for Supply.

Dangerous Substances and Explosive Atmospheres Regulations 2002 [L138]

Guidance Notes: Workplace Exposure Limits EH40. CHIP for everyone HSG(108).

EU Legislation

Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments.

National Regulations

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2002. No. 1689.

15.2. Chemical Safety Assessment

No chemical safety assessment has been carried out.

Revision Comments

Issued in new format for Reach compliance in accordance with EC 1272/2008 Issued in accordance with Annex II to REACH, as amended by Commission Regulation (EU) No. 453/2010 This is first issue.

Issued By Technical Dept. (P.E.)

Revision Date 20/10/2015

Revision 0

Supersedes date First Issue

SDS No. 11788

Safety Data Sheet Status Approved.

Date Date printed ____________________

Signature Initials ____________________

Risk Phrases In Full

R35 Causes severe burns.

R22 Harmful if swallowed.

R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

R36 Irritating to eyes.

R43 May cause sensitisation by skin contact.

NC Not classified.

R41 Risk of serious damage to eyes.

R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Hazard Statements In Full

H318 Causes serious eye damage.

H319 Causes serious eye irritation.

H314 Causes severe skin burns and eye damage.

H302 Harmful if swallowed.

H412 Harmful to aquatic life with long lasting effects.

H317 May cause an allergic skin reaction.

H411 Toxic to aquatic life with long lasting effects.

Disclaimer

This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company’s knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user’s responsibility to satisfy himself as to the suitability of such information for his own particular use.

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1.1. Product identifier

Product name TH/Q417 – WATER BASED FIRE VARNISH OVERCOAT – MATT
Product No. TH/Q417/20

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses Paint.

1.3. Details of the supplier of the safety data sheet

Supplier THERMOGUARD UK LTD
Kirkby Street
Hull
HU2 0BE
+44(0)1142 768008
+44(0)1624 825115
sales@thermoguard.co.uk
Contact Person Sales Department – 08.00 – 17.00 hrs Mon – Fri. as above

1.4. Emergency telephone number

+44 (0) 1142 768008 Thermoguard UK Ltd (08.00 – 17.00 hrs Mon – Fri)

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)
Physical and Chemical Hazards Not classified.
Human health Not classified.
Environment Not classified.
Classification (1999/45/EEC) Not classified.

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

2.2. Label elements

Label In Accordance With (EC) No. 1272/2008

No pictogram required.

Precautionary Statements:

P102 Keep out of reach of children.

P101 If medical advice is needed, have product container or label at hand.

P262 Do not get in eyes, on skin, or on clothing.

P271 Use only outdoors or in a well-ventilated area.

P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P337+313 If eye irritation persists: Get medical advice/attention.

P501 Dispose of contents/container in accordance with national regulations.

Supplemental label information: 
EUH208 Contains 2,4,7,9-TETRAMETHYLDEC-5-YNE-4,7-DIOL. May produce an allergic reaction.

2.3. Other hazards

3.2. Mixtures

Mixture of branched and linear C7-C9 alkyl 3-[3-(2H-benzotrizol-2-yl)-5-(1,1-demethylethyl)-4-hydroxyphenyl]propionates 1-5%
CAS-No.: 127519-17-9
EC No.: 407-000-3
Classification (67/548/EEC) N;R51/53.
Classification (EC 1272/2008) Aquatic Chronic 2 – H411
Registration Number: 01-0000015648-61

2-(2-BUTOXYETHOXY)ETHANOL <1% CAS-No.: 112-34-5 EC No.: 203-961-6 Classification (67/548/EEC) Xi;R36 Classification (EC 1272/2008) Eye Irrit. 2 - H319 Registration Number: 01-2119475104-44-0002 2,4,7,9-TETRAMETHYLDEC-5-YNE-4,7-DIOL <1% CAS-No.: 126-86-3 EC No.: 204-809-1 Classification (67/548/EEC) Xi;R41. R43,R52/53. Classification (EC 1272/2008) Eye Dam. 1 - H318; Skin Sens. 1 - H317; Aquatic Chronic 3 - H412 Registration Number: 01-2119954390-39 ETHANEDIOL <1% CAS-No.: 107-21-1 EC No.: 203-473-3 Classification (67/548/EEC) Xn;R22 Classification (EC 1272/2008) Acute Tox. 4 - H302 Registration Number: 01-2119456816-28 FORMALDEHYDE …% <0.1% CAS-No.: 50-00-0 EC No.: 200-001-8 Classification (EC 1272/2008): Acute Tox. 3 - H301; Acute Tox. 3 - H311; Acute Tox. 3 - H331; Skin Corr. 1B - H314; Skin Sens. 1 - H317; Carc. 2 - H351; STOT SE 3 - H335 Classification (67/548/EEC): Carc. Cat. 3;R40 - T;R23/24/25 - C;R34 - R43 SODIUM HYDROXIDE <0.1% CAS-No.: 1310-73-2 EC No.: 215-185-5 Classification (EC 1272/2008) Skin Corr. 1A - H314 Classification (67/548/EEC) C;R35 The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. [/fusion_toggle][fusion_toggle title="SECTION 4: FIRST AID MEASURES" open="no"]

4.1. Description of first aid measures

General information: General first aid, rest, warmth and fresh air. Do not give victim anything to drink if they are unconscious.

Inhalation: Remove victim immediately from source of exposure. Provide rest, warmth and fresh air. Get medical attention if any discomfort continues. Place unconscious person on the side in the recovery position and ensure breathing can take place.

Ingestion: DO NOT induce vomiting. Get medical attention immediately. Provide fresh air, warmth and rest, preferably in comfortable upright sitting position.

Skin contact: Remove affected person from source of contamination. Remove contaminated clothing immediately and wash skin with soap and water.

Eye contact: Make sure to remove any contact lenses from the eyes before rinsing. Continue to rinse for at least 15 minutes and get medical attention.

4.2. Most important symptoms and effects, both acute and delayed

General information: If adverse symptoms develop as described the casualty should be transferred to hospital as soon as possible.

4.3. Indication of any immediate medical attention and special treatment needed

No specific first aid measures noted.

5.1. Extinguishing media

Extinguishing media: Extinguish with foam, carbon dioxide, dry powder or water fog. Do not use water jet as an extinguisher, as this will spread the fire.

5.2. Special hazards arising from the substance or mixture

Specific hazards: The product is non-combustible. If heated, corrosive and toxic vapours/gases may be formed.

5.3. Advice for firefighters

Special Fire Fighting Procedures: Avoid breathing fire vapours. Do not allow runoff to sewer, waterway or ground. Cool containers exposed to flames with water until well after the fire is out.

Protective equipment for fire-fighters: Selection of respiratory protection for fire fighting: follow the general fire precautions indicated in the workplace.

6.1. Personal precautions, protective equipment and emergency procedures

Avoid inhalation of vapours and contact with skin and eyes. Provide adequate ventilation. Wear protective clothing as described in Section 8 of this safety data sheet.

6.2. Environmental precautions

Avoid discharge into drains, water courses or onto the ground. Contain spillages with sand, earth or any suitable adsorbent material. Spillages or uncontrolled discharges into watercourses must be IMMEDIATELY alerted to the Environmental Agency or other appropriate regulatory body.

6.3. Methods and material for containment and cleaning up

Should be prevented from entering drains. Absorb in vermiculite, dry sand or earth and place into containers. Collect spillage in containers, seal securely and deliver for disposal according to local regulations.

6.4. Reference to other sections

For personal protection, see section 8.

7.1. Precautions for safe handling

Keep away from heat, sparks and open flame. Avoid spilling, skin and eye contact. Avoid inhalation of vapours and spray mists. Do not eat, drink or smoke when using the product. Good personal hygiene is necessary. Wash hands and contaminated areas with water and soap before leaving the work site. The Manual Handling Operations Regulations may apply to the handling of containers of this product. To assist employers, the following method of calculating the weight for any pack size is given. Take the pack size volume in litres and multiply this figure by the specific gravity value given in section 9. This will give the net weight of the coating in kilograms. Allowance will then have to be made for the immediate packaging to give an approximate gross weight.

7.2. Conditions for safe storage, including any incompatibilities

Store in closed original container at temperatures between 5°C and 25°C. Keep away from heat, sparks and open flame. Protect from freezing and direct sunlight. Keep containers tightly closed. Keep upright. Store separated from: Oxidising material. Alkalis. Acids.

7.3. Specific end use(s)

The identified uses for this product are detailed in Section 1.2.

Usage Description: Ensure that waste and contaminated materials are collected and removed from the work area as soon as possible in a suitably labelled container.

8.1. Control parameters

8.2. Exposure controls

Protective equipment: Goggles & Gloves

Engineering measures: Provide adequate ventilation. Observe Occupational Exposure Limits and minimise the risk of inhalation of vapours.

Respiratory equipment: No specific recommendation made, but protection against nuisance dust must be used when the general level exceeds 10 mg/m3. Wear mask supplied with: Dust filter P2 (for fine dust).

Hand protection: Use suitable protective gloves if risk of skin contact. Use protective gloves made of: Neoprene, nitrile, polyethylene or PVC. Be aware that the liquid may penetrate the gloves. Frequent change is advisable. The most suitable glove must be chosen in consultation with the gloves supplier, who can inform about the breakthrough time of the glove material. Barrier cream applied before work may make it easier to clean the skin after exposure, but does not prevent absorption through the skin.

Eye protection: Wear approved, tight fitting safety glasses where splashing is probable.

Other Protection: Wear appropriate clothing to prevent reasonably probable skin contact.

Hygiene measures: No specific hygiene procedures noted, but good personal hygiene practices are always advisable, especially when working with chemicals.

9.1. Information on basic physical and chemical properties

Appearance: Creamy liquid.

Colour: White / off-white.

Solubility: Miscible with water

Initial boiling point and boiling range (°C): >100 760 mm Hg

Relative density 1.17 – 1.19 @ 20 °C

pH-Value, Conc. Solution: 4 – 5

Viscosity: 1.6 – 1.8 (ICI Rotothinner) Ps @ 25 °C

9.2. Other information

Volatile By Vol. (%): 65

Volatile Organic Compound (VOC):

10.1. Reactivity

No specific reactivity hazards associated with this product.

10.2. Chemical stability

Stable under normal temperature conditions and recommended use.

10.3. Possibility of hazardous reactions

Not determined.

10.4. Conditions to avoid

Avoid heat, flames and other sources of ignition. Avoid contact with acids and oxidising substances.

10.5. Incompatible materials

Materials To Avoid: Strong alkalis. Strong acids. Strong oxidising substances.

10.6. Hazardous decomposition products

Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours.

11.1. Information on toxicological effects

Toxicological information: No data recorded.

General information: No specific health warnings noted.

Inhalation: No specific health warnings noted.

Ingestion: No harmful effects expected in amounts likely to be ingested by accident.

Skin contact: Prolonged contact may cause dryness of the skin.

Eye contact: May cause temporary eye irritation.

Health Warnings: This product has low toxicity. Only large volumes may have adverse impact on human health.

Route of entry: Skin absorption. Ingestion. Skin and/or eye contact.

Medical Considerations: Skin disorders and allergies.

Ecotoxicity: There are no data on the ecotoxicity of this product.

12.1. Toxicity

12.2. Persistence and degradability

Degradability: The product is expected to be biodegradable.

12.3. Bioaccumulative potential

Bioaccumulative potential: No data available on bioaccumulation.

12.4. Mobility in soil

Mobility: The product contains substances, which are water soluble and may spread in water systems.

12.5. Results of PBT and vPvB assessment

12.6. Other adverse effects

Not determined.

General information: Do not allow to enter drains, sewers or watercourses. Waste to be treated as controlled waste. Disposal to licensed waste disposal site in accordance with local Waste Disposal Authority.

13.1. Waste treatment methods

Do not allow runoff to sewer, waterway or ground.

Waste Class: When this coating, in its liquid state, as supplied, becomes a waste, it is categorised as non-hazardous waste, with code 08 01 12 (WATER BASED LIQUID WASTE). Part used containers, not drained and/or rigorously scraped out and containing dry residues of the supplied coating, are categorised as non-hazardous waste, with code 08 01 12 (WATER BASED LIQUID WASTE). If mixed with other wastes, the above waste code may not be applicable. Used containers, drained and/or rigorously scraped out and containing dry residues of the supplied coating, are categorised as non-hazardous waste, with code 15 01 02 (plastic packaging) or 15 01 04 (metal packaging).

General The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA, ADR/RID).

14.1. UN number

Not applicable.

14.2. UN proper shipping name

Not applicable.

14.3. Transport hazard class(es)

Not applicable.

14.4. Packing group

Not applicable.

14.5. Environmental hazards

Environmentally Hazardous Substance/Marine Pollutant: No.

14.6. Special precautions for user

No information required.

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

Not applicable.

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

UK Regulatory References

The Control of Substances Hazardous to Health Regulations 2002 (S.I 2002 No. 2677) with amendments.

Statutory Instruments

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). Control of Substances Hazardous to Health.

Approved Code Of Practice

Safety Data Sheets for Substances and Preparations. Classification and Labelling of Substances and Preparations Dangerous for Supply.

Dangerous Substances and Explosive Atmospheres Regulations 2002 [L138]

Guidance Notes

Workplace Exposure Limits EH40. CHIP for everyone HSG(108).

EU Legislation

Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments.

National Regulations

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2002. No. 1689.

15.2. Chemical Safety Assessment

No chemical safety assessment has been carried out.

Revision Comments

Issued in new format for Reach compliance in accordance with EC 1272/2008 Issued in accordance with Annex II to REACH, as amended by Commission Regulation (EU) No. 453/2010 This is first issue.

Issued By Technical Dept. (P.E.)

Revision Date 16/06/2015

Revision 0

Supersedes date First Issue

SDS No. 11770

Safety Data Sheet Status Approved.

Date Date printed ____________________

Signature Initials ____________________

Risk Phrases In Full

R34 Causes burns.

R35 Causes severe burns.

R22 Harmful if swallowed.

R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

R36 Irritating to eyes.

R37 Irritating to respiratory system.

R40 Limited evidence of a carcinogenic effect.

R43 May cause sensitisation by skin contact.

NC Not classified.

R41 Risk of serious damage to eyes.

R23/24/25 Toxic by inhalation, in contact with skin and if swallowed.

R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Hazard Statements In Full

H318 Causes serious eye damage.

H319 Causes serious eye irritation.

H314 Causes severe skin burns and eye damage.

H302 Harmful if swallowed.

H412 Harmful to aquatic life with long lasting effects.

H317 May cause an allergic skin reaction.

H335 May cause respiratory irritation.

H351 Suspected of causing cancer.

H331 Toxic if inhaled.

H301 Toxic if swallowed.

H311 Toxic in contact with skin.

H411 Toxic to aquatic life with long lasting effects.

Disclaimer

This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company’s knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user’s responsibility to satisfy himself as to the suitability of such information for his own particular use.

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1.1. Product identifier

Product name TH/Q417 – WATER BASED FIRE VARNISH OVERCOAT – SATIN

Product No. TH/Q417/23

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses Paint.

1.3. Details of the supplier of the safety data sheet

Supplier THERMOGUARD UK LTD
Kirkby Street
Hull
HU2 0BE
+44(0)1142 768008
+44(0)1624 825115
sales@thermoguard.co.uk
Contact Person Sales Department – 08.00 – 17.00 hrs Mon – Fri. as above

1.4. Emergency telephone number

+44 (0) 1142 678008 Thermoguard UK Ltd (08.00 – 17.00 hrs Mon – Fri)

2.1. Classification of the substance or mixture

Classification (EC 1272/2008):

Physical and Chemical Hazards Not classified.
Human health Not classified.
Environment Not classified.
Classification (1999/45/EEC) Not classified.

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

2.2. Label elements

Label In Accordance With (EC) No. 1272/2008
No pictogram required.

Precautionary Statements:

P102 Keep out of reach of children.

P101 If medical advice is needed, have product container or label at hand.

P262 Do not get in eyes, on skin, or on clothing.

P271 Use only outdoors or in a well-ventilated area.

P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P337+313 If eye irritation persists: Get medical advice/attention.

P501 Dispose of contents/container in accordance with national regulations.

Supplemental label information:

EUH208 Contains 2,4,7,9-TETRAMETHYLDEC-5-YNE-4,7-DIOL. May produce an allergic reaction.

2.3. Other hazards

3.2. Mixtures

Mixture of branched and linear C7-C9 alkyl 3-[3-(2H-benzotrizol-2-yl)-5-(1,1-demethylethyl)-4-hydroxyphenyl]propionates 1-5%
CAS-No.: 127519-17-9
EC No.: 407-000-3
Classification (67/548/EEC): N;R51/53.
Classification (EC 1272/2008): Aquatic Chronic 2 – H411
Registration Number: 01-0000015648-61

2-(2-BUTOXYETHOXY)ETHANOL <1% CAS-No.: 112-34-5 EC No.: 203-961-6 Classification (67/548/EEC): Xi;R36 Classification (EC 1272/2008): Eye Irrit. 2 - H319 Registration Number: 01-2119475104-44-0002 2,4,7,9-TETRAMETHYLDEC-5-YNE-4,7-DIOL <1% CAS-No.: 126-86-3 EC No.: 204-809-1 Classification (67/548/EEC): Xi;R41. R43,R52/53. Classification (EC 1272/2008): Eye Dam. 1 - H318 Skin Sens. 1 - H317 Aquatic Chronic 3 - H412 Registration Number: 01-2119954390-39 ETHANEDIOL <1% CAS-No.: 107-21-1 EC No.: 203-473-3 Classification (67/548/EEC): Xn;R22 Classification (EC 1272/2008): Acute Tox. 4 - H302 Registration Number: 01-2119456816-28 FORMALDEHYDE …% <0.1% CAS-No.: 50-00-0 EC No.: 200-001-8 Classification (67/548/EEC): Carc. Cat. 3;R40 T;R23/24/25 C;R34 R43 Classification (EC 1272/2008): Acute Tox. 3 - H301 Acute Tox. 3 - H311 Acute Tox. 3 - H331 Skin Corr. 1B - H314 Skin Sens. 1 - H317 Carc. 2 - H351 STOT SE 3 - H335 SODIUM HYDROXIDE <0.1% CAS-No.: 1310-73-2 EC No.: 215-185-5 Classification (67/548/EEC): C;R35 Classification (EC 1272/2008): Skin Corr. 1A - H314 The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. [/fusion_toggle][fusion_toggle title="SECTION 4: FIRST AID MEASURES" open="no"]

4.1. Description of first aid measures

General information: General first aid, rest, warmth and fresh air. Do not give victim anything to drink if they are unconscious.

Inhalation: Remove victim immediately from source of exposure. Provide rest, warmth and fresh air. Get medical attention if any discomfort continues. Place unconscious person on the side in the recovery position and ensure breathing can take place.

Ingestion: DO NOT induce vomiting. Get medical attention immediately. Provide fresh air, warmth and rest, preferably in comfortable upright sitting position.

Skin contact: Remove affected person from source of contamination. Remove contaminated clothing immediately and wash skin with soap and water.

Eye contact: Make sure to remove any contact lenses from the eyes before rinsing. Continue to rinse for at least 15 minutes and get medical attention.

4.2. Most important symptoms and effects, both acute and delayed

General information: If adverse symptoms develop as described the casualty should be transferred to hospital as soon as possible.

4.3. Indication of any immediate medical attention and special treatment needed

No specific first aid measures noted.

5.1. Extinguishing media

Extinguishing media: Extinguish with foam, carbon dioxide, dry powder or water fog. Do not use water jet as an extinguisher, as this will spread the fire.

5.2. Special hazards arising from the substance or mixture

Specific hazards: The product is non-combustible. If heated, corrosive and toxic vapours/gases may be formed.

5.3. Advice for firefighters

Special Fire Fighting Procedures: Avoid breathing fire vapours. Do not allow runoff to sewer, waterway or ground. Cool containers exposed to flames with water until well after the fire is out.

Protective equipment for fire-fighters: Selection of respiratory protection for fire fighting: follow the general fire precautions indicated in the workplace.

6.1. Personal precautions, protective equipment and emergency procedures

Avoid inhalation of vapours and contact with skin and eyes. Provide adequate ventilation. Wear protective clothing as described in Section 8 of this safety data sheet.

6.2. Environmental precautions

Avoid discharge into drains, water courses or onto the ground. Contain spillages with sand, earth or any suitable adsorbent material. Spillages or uncontrolled discharges into watercourses must be IMMEDIATELY alerted to the Environmental Agency or other appropriate regulatory body.

6.3. Methods and material for containment and cleaning up

Should be prevented from entering drains. Absorb in vermiculite, dry sand or earth and place into containers. Collect spillage in containers, seal securely and deliver for disposal according to local regulations.

6.4. Reference to other sections

For personal protection, see section 8.

7.1. Precautions for safe handling

Keep away from heat, sparks and open flame. Avoid spilling, skin and eye contact. Avoid inhalation of vapours and spray mists. Do not eat, drink or smoke when using the product. Good personal hygiene is necessary. Wash hands and contaminated areas with water and soap before leaving the work site. The Manual Handling Operations Regulations may apply to the handling of containers of this product.

To assist employers, the following method of calculating the weight for any pack size is given. Take the pack size volume in litres and multiply this figure by the specific gravity value given in section 9. This will give the net weight of the coating in kilograms. Allowance will then have to be made for the immediate packaging to give an approximate gross weight.

7.2. Conditions for safe storage, including any incompatibilities

Store in closed original container at temperatures between 5°C and 25°C. Keep away from heat, sparks and open flame. Protect from freezing and direct sunlight. Keep containers tightly closed. Keep upright. Store separated from: Oxidising material. Alkalis. Acids.

7.3. Specific end use(s)

The identified uses for this product are detailed in Section 1.2.

Usage Description: Ensure that waste and contaminated materials are collected and removed from the work area as soon as possible in a suitably labelled container.

8.1. Control parameters

WEL = Workplace Exposure Limit.

8.2. Exposure controls

Protective equipment: Goggles & Gloves

Engineering measures: Provide adequate ventilation. Observe Occupational Exposure Limits and minimise the risk of inhalation of vapours.

Respiratory equipment: No specific recommendation made, but respiratory protection may still be required under exceptional circumstances when excessive air contamination exists.

Hand protection: Use suitable protective gloves if risk of skin contact. The most suitable glove must be chosen in consultation with the gloves supplier, who can inform about the breakthrough time of the glove material. Barrier cream applied before work may make it easier to clean the skin after exposure, but does not prevent absorption through the skin.

Eye protection: Wear approved, tight fitting safety glasses where splashing is probable.

Other Protection: Wear appropriate clothing to prevent reasonably probable skin contact.

Hygiene measures: No specific hygiene procedures noted, but good personal hygiene practices are always advisable, especially when working with chemicals.

9.1. Information on basic physical and chemical properties

Appearance: Creamy liquid.

Colour: White / off-white.

Solubility: Miscible with water

Initial boiling point and boiling range (°C): >100 760 mm Hg

Relative density: 1.17 – 1.19 @ 20 °C

pH-Value, Conc. Solution: 4 – 5

Viscosity: 1.6 – 1.8 (ICI Rotothinner) Ps @ 25 °C

9.2. Other information

Volatile By Vol. (%): 65

Volatile Organic Compound (VOC):

10.1. Reactivity

No specific reactivity hazards associated with this product.

10.2. Chemical stability

Stable under normal temperature conditions and recommended use.

10.3. Possibility of hazardous reactions

Not determined.

10.4. Conditions to avoid

Avoid heat, flames and other sources of ignition. Avoid contact with acids and oxidising substances.

10.5. Incompatible materials

Materials To Avoid: Strong alkalis. Strong acids. Strong oxidising substances.

10.6. Hazardous decomposition products

Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours.

11.1. Information on toxicological effects

Toxicological information: No data recorded.

General information: No specific health warnings noted.

Inhalation: No specific health warnings noted.

Ingestion: No harmful effects expected in amounts likely to be ingested by accident.

Skin contact: Prolonged contact may cause dryness of the skin.

Eye contact: May cause temporary eye irritation.

Health Warnings: This product has low toxicity. Only large volumes may have adverse impact on human health.

Route of entry: Skin absorption. Ingestion. Skin and/or eye contact.

Medical Considerations: Skin disorders and allergies.

Ecotoxicity: There are no data on the ecotoxicity of this product.

12.1. Toxicity

12.2. Persistence and degradability

Degradability: The product is expected to be biodegradable.

12.3. Bioaccumulative potential

Bioaccumulative potential: No data available on bioaccumulation.

12.4. Mobility in soil

Mobility: The product contains substances, which are water soluble and may spread in water systems.

12.5. Results of PBT and vPvB assessment

12.6. Other adverse effects

Not determined.

General information: Do not allow to enter drains, sewers or watercourses. Waste to be treated as controlled waste. Disposal to licensed waste disposal site in accordance with local Waste Disposal Authority.

13.1. Waste treatment methods

Do not allow runoff to sewer, waterway or ground.

Waste Class: When this coating, in its liquid state, as supplied, becomes a waste, it is categorised as non-hazardous waste, with code 08 01 12 (WATER BASED LIQUID WASTE). Part used containers, not drained and/or rigorously scraped out and containing dry residues of the supplied coating, are categorised as non-hazardous waste, with code 08 01 12 (WATER BASED LIQUID WASTE). If mixed with other wastes, the above waste code may not be applicable. Used containers, drained and/or rigorously scraped out and containing dry residues of the supplied coating, are categorised as non-hazardous waste, with code 15 01 02 (plastic packaging) or 15 01 04 (metal packaging).

General: The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA, ADR/RID).

14.1. UN number

Not applicable.

14.2. UN proper shipping name

Not applicable.

14.3. Transport hazard class(es)

Not applicable.

14.4. Packing group

Not applicable.

14.5. Environmental hazards

Environmentally Hazardous Substance/Marine Pollutant: No.

14.6. Special precautions for user

No information required.

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

Not applicable.

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Uk Regulatory References

The Control of Substances Hazardous to Health Regulations 2002 (S.I 2002 No. 2677) with amendments.

Statutory Instruments

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). Control of Substances Hazardous to Health.

Approved Code Of Practice

Safety Data Sheets for Substances and Preparations. Classification and Labelling of Substances and Preparations Dangerous for Supply.

Dangerous Substances and Explosive Atmospheres Regulations 2002 [L138]

Guidance Notes

Workplace Exposure Limits EH40. CHIP for everyone HSG(108).

EU Legislation

Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.

Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments.

National Regulations

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2002. No. 1689.

15.2. Chemical Safety Assessment

No chemical safety assessment has been carried out.

Revision Comments: Issued in new format for Reach compliance in accordance with EC 1272/2008 Issued in accordance with Annex II to REACH, as amended by Commission Regulation (EU) No. 453/2010 This is first issue.

Issued By Technical Dept. (P.E.)

Revision Date 16/06/2015

Revision 0

Supersedes date First Issue

SDS No. 11772

Safety Data Sheet Status Approved.

Date Date printed ____________________

Signature Initials ____________________

Risk Phrases In Full:

R34 Causes burns.

R35 Causes severe burns.

R22 Harmful if swallowed.

R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

R36 Irritating to eyes.

R37 Irritating to respiratory system.

R40 Limited evidence of a carcinogenic effect.

R43 May cause sensitisation by skin contact.

NC Not classified.

R41 Risk of serious damage to eyes.

R23/24/25 Toxic by inhalation, in contact with skin and if swallowed.

R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Hazard Statements In Full:

H318 Causes serious eye damage.

H319 Causes serious eye irritation.

H314 Causes severe skin burns and eye damage.

H302 Harmful if swallowed.

H412 Harmful to aquatic life with long lasting effects.

H317 May cause an allergic skin reaction.

H335 May cause respiratory irritation.

H351 Suspected of causing cancer.

H331 Toxic if inhaled.

H301 Toxic if swallowed.

H311 Toxic in contact with skin.

H411 Toxic to aquatic life with long lasting effects.

Disclaimer

This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company’s knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user’s responsibility to satisfy himself as to the suitability of such information for his own particular use.

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Important Application Notes

Thermoguard Fire Varnish system should only be applied to dry wood , with dry conditions during application & drying of basecoat and 1 coat of Overcoat
Thermoguard Fire Varnish basecoat is a water-based 2 pack coating .
Fire Varnish Overcoat should not be applied unless the basecoat is dry .
Drying time of basecoat in good conditions is overnight .
Once the basecoat has dried in good conditions the basecoat remains ideal to overcoat for a further 4 days 
NOTE: Thereafter , the basecoat becomes gradually harder , until it reaches a point where the Overcoat may not obtain a good bond .
Thermoguard therefore recommend overcoating when basecoat is dry , within the following 4 days in good conditions.
Delamination of Overcoat caused by application to near-full cured basecoat has NEVER occurred when Overcoat was applied within 7 days
The longer the delay beyond “4 days after basecoat has dried” (so typically 5 days after application )  , the greater the risk of Overcoat delaminating .
If overcoating is dalayed notably beyond 7 days after the basecoat was dry , we advise :-
  • basecoat is abraded to obtaing a key with 120 grit abrasive
  • apply a light coat of basecoat to replace material removed during abrasion
  • apply Overcoat within the ideal window or as near to it as possible

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