Project Description

Thermoguard Flame Retardant Anti-Graffiti is an effective anti-graffiti, decorative, flame retardant coating system for walls.

Water-based, high durability two-pack coating comprising Bonding Colourcoat & Clear Glaze designed to enable removal of graffiti through use of graffiti removers. Chemically cured coatings provide the highest resistance to oils, inks, crayon, marker and spray paints.

Upgrades high-flamespread-risk “multilayer” painted walls to Class O and new Class B s1 dO.

See Data Sheets and additional information below.

AVAILABLE IN:
5 kg packs

THERMOGUARD
Flame Retardant Anti-Graffiti

1.1. Product identifier

Product name TH/W222 – ANTI-GRAFFITI COLOURCOAT PASTEL BASE
Product No. TH/W222/P – Base

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses BASE FOR TWO COMPONENT ANTI-GRAFFITI COATING

1.3. Details of the supplier of the safety data sheet

Supplier THERMOGUARD UK LTD
Kirkby Street
Hull
HU2 0BE
+44(0)1142 768008
+44(0)1624 825115
sales@thermoguard.co.uk
Contact Person Sales Department – 08.00 – 17.00 hrs Mon – Fri. as above

1.4. Emergency telephone number

+44 (0) 1142 768008 Thermoguard UK Ltd (08.00 – 17.00 hrs Mon – Fri)

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)
Physical and Chemical Hazards Not classified.
Human health Skin Irrit. 2 – H315;Eye Irrit. 2 – H319;Skin Sens. 1 – H317
Environment Aquatic Chronic 2 – H411
Classification (1999/45/EEC) Xi;R36/38. R43. N;R51/53.

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

Human health

The product contains a small amount of sensitising substance which may provoke an allergic reaction among sensitive individuals in contact with skin.

Physical and Chemical Hazards

When handled correctly, undamaged units represent no danger.

2.2. Label elements

Contains REACTION PRODUCT : BISPHENOL A-(EPICHLOROHYDRIN):EPOXY RESIN (NUMBER AVERAGE MW<=700) FORMALDEHYDE, OLIGOMERIC REACTION PRODUCTS WITH 1-CHLORO-2,3-EPOXYPROPANE AND PHENOL OXIRANE, MONO [(C12-14- ALKYLOXY)METHYL] DERIVS Label In Accordance With (EC) No. 1272/2008

Signal Word Warning

Hazard Statements

H315 Causes skin irritation.

H317 May cause an allergic skin reaction.

H319 Causes serious eye irritation.

H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements

P273 Avoid release to the environment.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P302+352 IF ON SKIN: Wash with plenty of soap and water.

P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P313 Get medical advice/attention.

P501 Dispose of contents/container to …

Supplementary Precautionary Statements

P272 Contaminated work clothing should not be allowed out of the workplace.

P261 Avoid breathing vapour/spray.

P264 Wash contaminated skin thoroughly after handling.

P321 Specific treatment (see medical advice on this label).

P332+313 If skin irritation occurs: Get medical advice/attention.

P333+313 If skin irritation or rash occurs: Get medical advice/attention.

P337 If eye irritation persists:

P362 Take off contaminated clothing and wash before reuse.

P363 Wash contaminated clothing before reuse.

P391 Collect spillage.

Supplemental label information

EUH205 Contains epoxy constituents. May produce an allergic reaction.

2.3. Other hazards

3.2. Mixtures

REACTION PRODUCT : BISPHENOL A-(EPICHLOROHYDRIN):EPOXY RESIN (NUMBER AVERAGE MW<=700) 30-60%
CAS-No.: 25068-38-6
EC No.: 500-033-5
Classification (67/548/EEC):
R43
Xi;R36/38
N;R51/53
Classification (EC 1272/2008):
Skin Irrit. 2 – H315
Eye Irrit. 2 – H319
Skin Sens. 1 – H317
Aquatic Chronic 2 – H411

Titanium Dioxide 10-30%
CAS-No.: 13463-67-7
EC No.: 236-675-5
Classification (67/548/EEC): Not classified.
Classification (EC 1272/2008): Not classified.
Registration Number: 01-2119489379-17-xxxx

Barium Sulphate 10-30%
CAS-No.: 7727-43-7
EC No.: 231-784-4
Classification (67/548/EEC): Not classified.
Classification (EC 1272/2008): Not classified.
Registration Number: 01-2119491274-35-0001

FORMALDEHYDE, OLIGOMERIC REACTION PRODUCTS WITH 1-CHLORO-2,3-EPOXYPROPANE AND PHENOL 10-30%
CAS-No.: 9003-36-5
EC No.: 500-006-8
Classification (67/548/EEC):
Xi;R38.
N;R51/53.
R43.
Classification (EC 1272/2008):
Skin Irrit. 2 – H315
Skin Sens. 1 – H317
Aquatic Chronic 2 – H411

Calcium Magnesium Silicate 10-30%
CAS-No.: 14807-96-6
EC No.: 238-877-9
Classification (67/548/EEC): Not classified.
Classification (EC 1272/2008): Not classified.

OXIRANE, MONO [(C12-14- ALKYLOXY)METHYL] DERIVS 5-10%
CAS-No.: 68609-97-2
EC No.:
Classification (67/548/EEC):
R43
Xi;R38
Classification (EC 1272/2008):
Skin Irrit. 2 – H315
Skin Sens. 1 – H317

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

4.1. Description of first aid measures

General information: General first aid, rest, warmth and fresh air. Do not give victim anything to drink if they are unconscious.

Inhalation: Remove victim immediately from source of exposure. Provide rest, warmth and fresh air. Get medical attention if any discomfort continues. Place unconscious person on the side in the recovery position and ensure breathing can take place.

Ingestion: Immediately give a couple of glasses of water or milk, provided the victim is fully conscious. Do not induce vomiting. Get medical attention if any discomfort continues.

Skin contact: Remove affected person from source of contamination. Wash off promptly and flush contaminated skin with water. Promptly remove clothing if soaked through and flush skin with water. Get medical attention if irritation persists after washing.

Eye contact: Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyes wide apart. Get medical attention immediately. Continue to rinse.

4.2. Most important symptoms and effects, both acute and delayed

General information: If adverse symptoms develop as described the casualty should be transferred to hospital as soon as possible.

4.3. Indication of any immediate medical attention and special treatment needed

No recommendation given, but first aid may still be required in case of accidental exposure, inhalation or ingestion of this chemical. If in doubt, GET MEDICAL ATTENTION PROMPTLY!

5.1. Extinguishing media

Extinguishing media: Non flammable at room temperature, but will burn. Use fire-extinguishing media appropriate for surrounding materials. Fire can be extinguished using: Water spray, fog or mist. Foam, carbon dioxide or dry powder.

5.2. Special hazards arising from the substance or mixture

Specific hazards: When heated and in case of fire, harmful vapours/gases may be formed.

5.3. Advice for firefighters

Special Fire Fighting Procedures: Avoid breathing fire vapours. Containers close to fire should be removed or cooled with water.

Protective equipment for fire-fighters: Self contained breathing apparatus and full protective clothing must be worn in case of fire.

6.1. Personal precautions, protective equipment and emergency procedures

Avoid inhalation of vapours and contact with skin and eyes. Provide adequate ventilation. Wear protective clothing as described in Section 8 of this safety data sheet.

6.2. Environmental precautions

Avoid discharge into drains, water courses or onto the ground. Contain spillages with sand, earth or any suitable adsorbent material.

Spillages or uncontrolled discharges into watercourses must be IMMEDIATELY alerted to the Environmental Agency or other appropriate regulatory body.

6.3. Methods and material for containment and cleaning up

Should be prevented from entering drains. Absorb in vermiculite, dry sand or earth and place into containers. Collect spillage in containers, seal securely and deliver for disposal according to local regulations.

6.4. Reference to other sections

For personal protection, see section 8.

7.1. Precautions for safe handling

Avoid inhalation of vapours. Avoid spilling, skin and eye contact. Do not eat, drink or smoke when using the product. Good personal hygiene is necessary. Wash hands and contaminated areas with water and soap before leaving the work site. The Manual Handling Operations Regulations may apply to the handling of containers of this product. For products sold by weight refer to the guide net weight indicated on the container. Allowance will have to be made for the immediate packaging to give an approximate gross weight.

7.2. Conditions for safe storage, including any incompatibilities

Store in tightly closed original container in a dry, cool and well-ventilated place. Store in closed original container at temperatures between 5°C and 25°C. Protect from freezing and direct sunlight. Keep upright.

7.3. Specific end use(s)

The identified uses for this product are detailed in Section 1.2.

Usage Description: Ensure that waste and contaminated materials are collected and removed from the work area as soon as possible in a suitably labelled container.

8.1. Control parameters

8.2. Exposure controls

Protective equipment

Process conditions: Use engineering controls to reduce air contamination to permissible exposure level.

Engineering measures: Provide adequate ventilation. Observe Occupational Exposure Limits and minimise the risk of inhalation of vapours.

Respiratory equipment: No specific recommendation made, but respiratory protection may still be required under exceptional circumstances when excessive air contamination exists.

Hand protection: Use suitable protective gloves if risk of skin contact. The most suitable glove must be chosen in consultation with the gloves supplier, who can inform about the breakthrough time of the glove material. Barrier cream applied before work may make it easier to clean the skin after exposure, but does not prevent absorption through the skin.

Eye protection: Wear approved chemical safety goggles where eye exposure is reasonably probable.

Other Protection: Wear appropriate clothing to prevent reasonably probable skin contact.

Hygiene measures: No specific hygiene procedures noted, but good personal hygiene practices are always advisable, especially when working with chemicals.

Personal protection: Unprotected persons should be kept away from treated areas.

9.1. Information on basic physical and chemical properties

Appearance: Coloured liquid.
Colour: White / off-white.
Odour: Sweetish.
Solubility: Immiscible with water
Initial boiling point and boiling range (°C): >150 760 mm Hg
Relative density: 1.69 @ 25C
Vapour pressure: Viscosity: 10+ Ps @ 25 C
Auto Ignition Temperature (°C): >200

9.2. Other information

Volatile By Vol. (%): <1 Volatile Organic Compound (VOC): [/fusion_toggle][fusion_toggle title="SECTION 10: STABILITY AND REACTIVITY" open="no"]

10.1. Reactivity

No specific reactivity hazards associated with this product.

10.2. Chemical stability

Stable under normal temperature conditions and recommended use.

10.3. Possibility of hazardous reactions

Hazardous Polymerisation: Will not occur

10.4. Conditions to avoid

Not known.

10.5. Incompatible materials

Materials To Avoid: Strong acids. Bases, alkalis (inorganic). Amines. Mercaptans (thiols).

10.6. Hazardous decomposition products

Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours.

11.1. Information on toxicological effects

Toxicological information: No data recorded.

General information: No specific health warnings noted.

Inhalation: May cause irritation to the respiratory system.

Ingestion: Harmful if swallowed. Ingestion may cause severe irritation of the mouth, the oesophagus and the gastrointestinal tract.

Skin contact: Irritating to skin. May cause sensitisation by skin contact.

Eye contact: Irritating to eyes.

Health Warnings: May cause sensitisation by skin contact. Delayed appearance of the complaints and development of hypersensitivity (difficulty breathing, coughing, asthma) are possible.

Route of entry: Inhalation. Skin absorption. Ingestion. Skin and/or eye contact.

Medical Considerations: Skin disorders and allergies.

Toxicological information on ingredients.

REACTION PRODUCT : BISPHENOL A-(EPICHLOROHYDRIN):EPOXY RESIN (NUMBER AVERAGE MW<=700) (CAS: 25068-38-6)

Toxic Dose 1 – LD 50
11400 mg/kg (oral rat)
Toxic Dose 2 – LD 50
15600 mg/kg (oral-mouse)

Acute toxicity:
Acute Toxicity (Dermal LD50)
> 20 mg/kg Rabbit

Aspiration hazard:
Inhalation: Upper respiratory irritation.
Skin contact: Irritating to skin. May cause sensitisation by skin contact.
Irritating to eyes.

Ecotoxicity: There are no data on the ecotoxicity of this product.

Ecological information on ingredients.

REACTION PRODUCT : BISPHENOL A-(EPICHLOROHYDRIN):EPOXY RESIN (NUMBER AVERAGE MW<=700) (CAS: 25068-38-6)

Ecotoxicity: The product contains substances which are toxic to aquatic organisms and which may cause long term adverse effects in the aquatic environment.

12.1. Toxicity

Acute Fish Toxicity
Toxicity to bacteria, algae and higher marine organisms not tested. COD: Not determined

Ecological information on ingredients.

REACTION PRODUCT : BISPHENOL A-(EPICHLOROHYDRIN):EPOXY RESIN (NUMBER AVERAGE MW<=700) (CAS: 25068-38-6)

Acute Toxicity – Fish
LC50 96 hours 3.6 mg/l Leuciscus idus (Golden orfe)

Acute Toxicity – Aquatic Invertebrates
EC50 48 hours 2.8 mg/l Daphnia magna

Acute Toxicity – Aquatic Plants
EC50 96 hours 220 mg/l Freshwater algae

12.2. Persistence and degradability

Degradability: No data available.

Ecological information on ingredients.

REACTION PRODUCT : BISPHENOL A-(EPICHLOROHYDRIN):EPOXY RESIN (NUMBER AVERAGE MW<=700) (CAS: 25068-38-6)

Degradability: The product is not readily biodegradable.

12.3. Bioaccumulative potential

Bioaccumulative potential: No data available on bioaccumulation.

Ecological information on ingredients.

REACTION PRODUCT : BISPHENOL A-(EPICHLOROHYDRIN):EPOXY RESIN (NUMBER AVERAGE MW<=700) (CAS: 25068-38-6)

Bioaccumulative potential: No data available on bioaccumulation.

12.4. Mobility in soil

Mobility: The product is non-volatile.

Ecological information on ingredients.

REACTION PRODUCT : BISPHENOL A-(EPICHLOROHYDRIN):EPOXY RESIN (NUMBER AVERAGE MW<=700) (CAS: 25068-38-6)

Mobility: Not determined

12.5. Results of PBT and vPvB assessment

Ecological information on ingredients.

REACTION PRODUCT : BISPHENOL A-(EPICHLOROHYDRIN):EPOXY RESIN (NUMBER AVERAGE MW<=700) (CAS: 25068-38-6)

Not Classified as PBT/vPvB by current EU criteria.

12.6. Other adverse effects

Not determined.

Ecological information on ingredients.

REACTION PRODUCT : BISPHENOL A-(EPICHLOROHYDRIN):EPOXY RESIN (NUMBER AVERAGE MW<=700) (CAS: 25068-38-6)

Not determined.

General information: Do not allow to enter drains, sewers or watercourses. Waste to be treated as controlled waste. Disposal to licensed waste disposal site in accordance with local Waste Disposal Authority. When handling waste, consideration should be made to the safety precautions applying to handling of the product. DO NOT reuse containers containing residual product without commercial cleaning

13.1. Waste treatment methods

Waste Class: When this material, in its liquid state, as supplied, becomes a waste, it is categorised as a hazardous waste, with code 08 01 11* (EPOXY BASED LIQUID WASTE). Part-used containers, not drained and/or rigorously scraped out and containing residues of the supplied material, are categorised as hazardous waste, with code 08 01 11* (EPOXY BASED LIQUID WASTE). Ideally this component should be mixed with the appropriate hardener and allowed to react fully to produce a solid waste. Neutralised empty packages, are categorised as non-hazardous waste, with code 15 01 02(plastic packaging) or 15 01 04 (metal packaging)

General This product is packed in accordance with the Limited Quantity Provisions of CDGCPL2, ADR and IMDG.

14.1. UN number

UN No. (ADR/RID/ADN) 3082
UN No. (IMDG) 3082

14.2. UN proper shipping name

Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

14.3. Transport hazard class(es)

ADR/RID/ADN Class 9
ADR/RID/ADN Class Class 9: Environmentally hazardous substance, liquid, N.O.S. contains: epoxy constituents
ADR/RID/ADN Subsidiary Risk HAZARD ID 90
IMDG Class 9
ICAO Class/Division 9

Transport Labels

14.4. Packing group

ADR/RID/ADN Packing group III
IMDG Packing group III
ICAO Packing group III

14.5. Environmental hazards

Environmentally Hazardous Substance/Marine Pollutant

14.6. Special precautions for user

EMS F-A S-F
Tunnel Restriction Code (E)

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

Not applicable.

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

UK Regulatory References

The Control of Substances Hazardous to Health Regulations 2002 (S.I 2002 No. 2677) with amendments.

Statutory Instruments

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). Control of Substances Hazardous to Health.

Approved Code Of Practice

Safety Data Sheets for Substances and Preparations. Classification and Labelling of Substances and Preparations Dangerous for Supply.

Dangerous Substances and Explosive Atmospheres Regulations 2002 [L138]

Guidance Notes

Workplace Exposure Limits EH40. CHIP for everyone HSG(108).

EU Legislation

Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments.

National Regulations

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2002. No. 1689.

15.2. Chemical Safety Assessment

No chemical safety assessment has been carried out.

Revision Comments

This is first issue. Issued in new format for Reach compliance in accordance with EC 1272/2008 Issued in accordance with Annex II to REACH, as amended by Commission Regulation (EU) No. 453/2010

Issued By Technical Dept. (P.E.)

Revision Date 03/11/2014

Revision 0

Supersedes date First issue

SDS No. 11720

Safety Data Sheet Status Approved.

Date Date printed ____________________

Signature Initials ____________________

Risk Phrases In Full

R36/38 Irritating to eyes and skin.

R38 Irritating to skin.

R43 May cause sensitisation by skin contact.

NC Not classified.

R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Hazard Statements In Full

H319 Causes serious eye irritation.

H315 Causes skin irritation.

H317 May cause an allergic skin reaction.

H411 Toxic to aquatic life with long lasting effects.

Disclaimer

This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company’s knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user’s responsibility to satisfy himself as to the suitability of such information for his own particular use.

1.1. Product identifier

Product name TH/W222 – ANTI-GRAFFITI COLOURCOAT – ACTIVATOR
Product No. TH/W222/H – Activator

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses HARDENER FOR TWO COMPONENT ANTI-GRAFFITI COATING

1.3. Details of the supplier of the safety data sheet

Supplier THERMOGUARD UK LTD
Kirkby Street
Hull
HU2 0BE
+44(0)1142 768008
+44(0)1624 825115
sales@thermoguard.co.uk
Contact Person Sales Department – 08.00 – 17.00 hrs Mon – Fri. as above

1.4. Emergency telephone number

+44 (0) 1482 328053 (08.30 – 16.30 hrs Mon – Thurs, 08.30 – 15.00 hrs Fri)

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)
Physical and Chemical Hazards Not classified.
Human health Eye Dam. 1 – H318;Skin Sens. 1 – H317
Environment Not classified.
Classification (1999/45/EEC) Xi;R41. R43.

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

2.2. Label elements

Contains m-phenylenebis(methylamine)

Label In Accordance With (EC) No. 1272/2008

Signal Word Danger

Hazard Statements

H317 May cause an allergic skin reaction.

H318 Causes serious eye damage.

Precautionary Statements

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P310 Immediately call a POISON CENTER or doctor/physician.

Supplementary Precautionary Statements

P272 Contaminated work clothing should not be allowed out of the workplace.

P261 Avoid breathing vapour/spray.

P321 Specific treatment (see medical advice on this label).

P302+352 IF ON SKIN: Wash with plenty of soap and water.

P333+313 If skin irritation or rash occurs: Get medical advice/attention.

P363 Wash contaminated clothing before reuse.

P501 Dispose of contents/container to …

Supplemental label information

EUH205 Contains epoxy constituents. May produce an allergic reaction.

2.3. Other hazards

3.2. Mixtures

Polymer, reaction product of BADGE/glycidylether with TEPA 10-30%
CAS-No.: 155240-10-1
EC No.:
Classification (67/548/EEC): Xi;R41.
Classification (EC 1272/2008): Eye Dam. 1 – H318

Parafins (petroleum), normal C5-C20 5-10%
CAS-No.: 64771-72-8
EC No.: 265-233-4
Classification (67/548/EEC):
Xn;R65.
R66.
Classification (EC 1272/2008): Asp. Tox. 1 – H304
Registration Number: 01-2119475608-26

Poly(oxy-1,2-ethanediyl), a-(carboxymethyl)-w-hydroxy-, C12-C14-alkyl ethers 1-5%
CAS-No.: 220622-96-8
EC No.:
Classification (67/548/EEC): Xi;R41,R38.
Classification (EC 1272/2008):
Skin Irrit. 2 – H315
Eye Dam. 1 – H318

m-phenylenebis(methylamine) 1-5%
CAS-No.: 1477-55-0
EC No.: 216-032-5
Classification (67/548/EEC):
Xn;R20/22.
C;R34.
R43,R52/53.
Classification (EC 1272/2008):
Acute Tox. 4 – H302
Acute Tox. 3 – H331
Skin Corr. 1B – H314
Skin Sens. 1 – H317
Aquatic Chronic 3 – H412
Registration Number: 01-2119480150-50

SULPHAMIC ACID 1-5%
CAS-No.: 5329-14-6
EC No.: 226-218-8
Classification (67/548/EEC):
Xi;R36/38
R52/53
Classification (EC 1272/2008):
Skin Irrit. 2 – H315
Eye Irrit. 2 – H319
Aquatic Chronic 3 – H412

3-(Polyoxyethylene)propylheptamethyltrisiloxane <1% CAS-No.: 67674-67-3 EC No.: Classification (67/548/EEC): Xn;R20. Xi;R41. N;R51/53. Classification (EC 1272/2008): Acute Tox. 4 - H332 Eye Dam. 1 - H318 Aquatic Chronic 2 - H411 The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. [/fusion_toggle][fusion_toggle title="SECTION 4: FIRST AID MEASURES" open="no"]

4.1. Description of first aid measures

General information: General first aid, rest, warmth and fresh air. Do not give victim anything to drink if they are unconscious.

Inhalation: Move the exposed person to fresh air at once. Get medical attention if any discomfort continues.

Ingestion: Immediately rinse mouth and drink plenty of water. If person becomes uncomfortable or if ingested in large amounts (50-100 ml for an adult person): Take to hospital along with these instructions. Do not induce vomiting. NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS!

Skin contact: Remove contaminated clothing. Wash the skin immediately with soap and water. Get medical attention if irritation persists after washing.

Eye contact: Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyelids widely. If irritation persists: Continue flushing during transport to hospital. Bring these instructions.

4.2. Most important symptoms and effects, both acute and delayed

General information: If adverse symptoms develop as described the casualty should be transferred to hospital as soon as possible.

4.3. Indication of any immediate medical attention and special treatment needed

No recommendation given, but first aid may still be required in case of accidental exposure, inhalation or ingestion of this chemical. If in doubt, GET MEDICAL ATTENTION PROMPTLY!

5.1. Extinguishing media

Extinguishing media: This product is not flammable.

5.2. Special hazards arising from the substance or mixture

Specific hazards: The product is non-combustible. If heated, harmful vapours may be formed.

5.3. Advice for firefighters

Special Fire Fighting Procedures: Keep run-off water out of sewers and water sources. Dike for water control. Avoid breathing fire vapours.

Protective equipment for fire-fighters: Self contained breathing apparatus and full protective clothing must be worn in case of fire.

6.1. Personal precautions, protective equipment and emergency procedures

Exclude non-essential personnel. Wear protective clothing as described in Section 8 of this safety data sheet. Avoid inhalation of vapours and contact with skin and eyes.

6.2. Environmental precautions

Avoid discharge to the aquatic environment. Spillages or uncontrolled discharges into watercourses must be IMMEDIATELY alerted to the Environmental Agency or other appropriate regulatory body.

6.3. Methods and material for containment and cleaning up

Stop leak if possible without risk. Neutralise with dilute aqueous acid, such as acetic acid. Neutralisation reaction is exothermic. Flush with plenty of water to clean spillage area. Do not contaminate water sources or sewer. For waste disposal, see section 13.

6.4. Reference to other sections

For personal protection, see section 8.

7.1. Precautions for safe handling

Avoid inhalation of vapours/spray and contact with skin and eyes. Good personal hygiene is necessary. Wash hands and contaminated areas with water and soap before leaving the work site. Persons with a history of skin sensitisation problems should not be employed in a situation where skin contact with this product could occur, nor should those with asthma or similar disorders be exposed to the vapour or spray mist.

The Manual Handling Operations Regulations may apply to the handling of containers of this product. To assist employers, the following method of calculating the weight for any pack size is given. Take the pack size volume in litres and multiply this figure by the specific gravity value given in section 9. This will give the net weight of the coating in kilograms. Allowance will then have to be made for the immediate packaging to give an approximate gross weight.

7.2. Conditions for safe storage, including any incompatibilities

Keep upright. Store in tightly closed original container in a dry and cool place.

Storage Class: Chemical storage.

7.3. Specific end use(s)

The identified uses for this product are detailed in Section 1.2.

8.1. Control parameters

8.2. Exposure controls

Protective equipment

Engineering measures: Provide adequate ventilation. Observe Occupational Exposure Limits and minimise the risk of inhalation of vapours.

Respiratory equipment: If ventilation is insufficient, suitable respiratory protection must be provided.

Hand protection: Use suitable protective gloves if risk of skin contact. Neoprene, nitrile, polyethylene or PVC. Barrier cream applied before work may make it easier to clean the skin after exposure, but does not prevent absorption through the skin.

Eye protection: Wear splash-proof eye goggles to prevent any possibility of eye contact.

Other Protection: Wear appropriate clothing to prevent reasonably probable skin contact. Provide eyewash station.

Hygiene measures: Wash hands at the end of each work shift and before eating, smoking and using the toilet. When using do not eat, drink or smoke.

9.1. Information on basic physical and chemical properties

Appearance: Viscous Liquid
Colour: Yellowish
Odour: Ammonia.
Solubility: Miscible with water
Initial boiling point and boiling range (°C): 760 mm Hg >100
Relative density: 1.01 @ 20 C
pH-Value, Conc. Solution: Alkaline
Flash point (°C): Water based

9.2. Other information

Volatile By Vol. (%): 65
Volatile Organic Compound (VOC): 27.5 g/litre

10.1. Reactivity

No specific reactivity hazards associated with this product.

10.2. Chemical stability

Stable under normal temperature conditions and recommended use.

10.3. Possibility of hazardous reactions

Not determined.

10.4. Conditions to avoid

Avoid contact with acids and oxidising substances.

10.5. Incompatible materials

Materials To Avoid: No incompatible groups noted.

10.6. Hazardous decomposition products

In case of fire, toxic gases (CO, CO2, NOx) may be formed.

11.1. Information on toxicological effects

Inhalation: In high concentrations, vapours may irritate throat and respiratory system and cause coughing.

Ingestion: Irritating. May cause nausea, stomach pain and vomiting.

Skin contact: Irritating to skin. Risk of sensitisation or allergic reactions among sensitive individuals.

Eye contact: Risk of serious damage to eyes. Irritating and may cause redness and pain.

Route of entry: Inhalation. Skin absorption. Ingestion. Skin and/or eye contact.

Toxicological information on ingredients.

m-phenylenebis(methylamine) (CAS: 1477-55-0)

Toxic Dose 1 – LD 50
930 mg/kg (oral rat)
Toxic Conc. – LC 50
2.4 mg/l/4h (inh-rat)

Acute toxicity:
Acute Toxicity (Dermal LD50)
2000 mg/kg Rabbit

Aspiration hazard:
Skin contact
Irritating to skin. May cause sensitisation by skin contact.
Irritation of eyes and mucous membranes. Risk of serious damage to eyes.

Ecotoxicity: Dangerous for the environment if discharged into watercourses. The product contains a substance which may have adverse effects on waste water treatment processes. The product may affect the acidity (pH-factor) in water with risk of harmful effects to aquatic organisms.

12.1. Toxicity

Dangerous for the environment if discharged into watercourses

Ecological information on ingredients.

m-phenylenebis(methylamine) (CAS: 1477-55-0)

Acute Toxicity – Fish
LC50 96 hours > 100 mg/l Brachydanio rerio (Zebra Fish)
LC50 96 hours > 100 mg/l Onchorhynchus mykiss (Rainbow trout)

Acute Toxicity – Aquatic Invertebrates
EC50 48 hours 16 mg/l Daphnia magna

Acute Toxicity – Aquatic Plants
EC50 72 hours 12 mg/l Scenedesmus subspicatus

12.2. Persistence and degradability

Degradability: There are no data on the degradability of this product.

12.3. Bioaccumulative potential

Bioaccumulative potential: No data available on bioaccumulation.

Ecological information on ingredients.

SULPHAMIC ACID (CAS: 5329-14-6)

Partition coefficient: log Pow 0.101

m-phenylenebis(methylamine) (CAS: 1477-55-0)

Bioaccumulation factor: BCF 2.69134803
Partition coefficient: log Pow 0.18

12.4. Mobility in soil

Mobility: The product is partly miscible with water and may spread in the aquatic environment.

12.5. Results of PBT and vPvB assessment

Not Classified as PBT/vPvB by current EU criteria.

12.6. Other adverse effects

Not determined.

General information: Do not allow to enter drains, sewers or watercourses. Waste to be treated as controlled waste. Disposal to licensed waste disposal site in accordance with local Waste Disposal Authority.

13.1. Waste treatment methods

Dispose of waste and residues in accordance with local authority requirements. Do not allow runoff to sewer, waterway or ground.

Environmental manager must be informed of all major spillages.

Waste Class: When this material, in its liquid state, as supplied, becomes a waste, it is categorised as a hazardous waste, with code 08 01 11* (EPOXY BASED LIQUID WASTE). Part-used containers, not drained and/or rigorously scraped out and containing residues of the supplied material, are categorised as hazardous waste, with code 08 01 11* (EPOXY BASED LIQUID WASTE). Neutralised empty packages, are categorised as non-hazardous waste, with code 15 01 02(plastic packaging) or 15 01 04 (metal packaging)

General The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA, ADR/RID).

Sea Transport Notes Not classified.

14.1. UN number

Not applicable.

14.2. UN proper shipping name

Proper Shipping Name PAINT

14.3. Transport hazard class(es)

ADR/RID/ADN Class Not classified for transportation.
IMDG Class not classified

14.4. Packing group

Not applicable.

14.5. Environmental hazards

Environmentally Hazardous Substance/Marine Pollutant

No.

14.6. Special precautions for user

Not applicable.

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

Not applicable.

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

UK Regulatory References

The Control of Substances Hazardous to Health Regulations 2002 (S.I 2002 No. 2677) with amendments.

Statutory Instruments

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). Control of Substances Hazardous to Health.

Approved Code Of Practice

Safety Data Sheets for Substances and Preparations. Classification and Labelling of Substances and Preparations Dangerous for Supply.

Dangerous Substances and Explosive Atmospheres Regulations 2002 [L138]

Guidance Notes

Workplace Exposure Limits EH40. CHIP for everyone HSG(108).

EU Legislation

Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments.

National Regulations

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2002. No. 1689.

15.2. Chemical Safety Assessment

No chemical safety assessment has been carried out.

Revision Comments

This is first issue. Issued in new format for Reach compliance in accordance with EC 1272/2008 Issued in accordance with Annex II to REACH, as amended by Commission Regulation (EU) No. 453/2010

Issued By Technical Dept. (P.E.)

Revision Date 03/11/2014

Revision 0

Supersedes date First Issue

SDS No. 11721

Safety Data Sheet Status Approved.

Date Date printed ____________________

Signature Initials ____________________

Risk Phrases In Full

R34 Causes burns.

R20/22 Harmful by inhalation and if swallowed.

R20 Harmful by inhalation.

R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

R65 Harmful: may cause lung damage if swallowed.

R36/38 Irritating to eyes and skin.

R38 Irritating to skin.

R43 May cause sensitisation by skin contact.

R66 Repeated exposure may cause skin dryness or cracking.

R41 Risk of serious damage to eyes.

R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Hazard Statements In Full

H318 Causes serious eye damage.

H319 Causes serious eye irritation.

H314 Causes severe skin burns and eye damage.

H315 Causes skin irritation.

H332 Harmful if inhaled.

H302 Harmful if swallowed.

H412 Harmful to aquatic life with long lasting effects.

H304 May be fatal if swallowed and enters airways.

H317 May cause an allergic skin reaction.

H331 Toxic if inhaled.

H411 Toxic to aquatic life with long lasting effects.

Disclaimer

This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company’s knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user’s responsibility to satisfy himself as to the suitability of such information for his own particular use.

1.1. Product identifier

Product name TH/WB101 – FLAME RETARDANT ANTI-GRAFFITI COATING – CLEAR BASE
Product No. TH/WB101/T – BASE

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses BASE FOR TWO COMPONENT ANTI-GRAFFITI COATING For use as an an anti graffiti coating over Thermoguard Wallcoat or Thermoguard SFR Dualcoat.

Uses advised against NOT SUITABLE FOR FOR USE IN HOMEWORKER (DIY) APPLICATIONS

1.3. Details of the supplier of the safety data sheet

Supplier THERMOGUARD UK LTD
Kirkby Street
Hull
HU2 0BE
+44(0)1142 768008
+44(0)1624 825115
sales@thermoguard.co.uk
Contact Person Sales Department – 08.00 – 17.00 hrs Mon – Fri. as above

1.4. Emergency telephone number

+44 (0) 1142 768008 Thermoguard UK Ltd (08.00 – 17.00 hrs Mon – Fri)

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)
Physical and Chemical Hazards Flam. Liq. 3 – H226
Human health Skin Sens. 1 – H317
Environment Aquatic Chronic 3 – H412
Classification (1999/45/EEC) R43. R10, R52/53.

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

Human health: See section 11 for additional information on health hazards. The product contains a sensitising substance which may provoke an allergic reaction among sensitive individuals.

2.2. Label elements

Contains WATER THINNABLE POLYACRYLATE CONTAINING HYDROXYL GROUPS

Label In Accordance With (EC) No. 1272/2008

 

Signal Word Warning

Hazard Statements

H226 Flammable liquid and vapour.

H317 May cause an allergic skin reaction.

H412 Harmful to aquatic life with long lasting effects.

Precautionary Statements

P102 Keep out of reach of children.

P101 If medical advice is needed, have product container or label at hand.

P210 Keep away from heat/sparks/open flames/hot surfaces. – No smoking.

P233 Keep container tightly closed.

P262 Do not get in eyes, on skin, or on clothing.

P235 Keep cool.

P312 Call a POISON CENTER or doctor/physician if you feel unwell.

P501C Dispose of contents/container in accordance with national regulations.

Supplementary Precautionary Statements

P240 Ground/bond container and receiving equipment.

P241 Use explosion-proof electrical equipment.

P242 Use only non-sparking tools.

P243 Take precautionary measures against static discharge.

P272 Contaminated work clothing should not be allowed out of the workplace.

P273 Avoid release to the environment.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P261 Avoid breathing vapour/spray.

P321 Specific treatment (see medical advice on this label).

P370+378 In case of fire: Use foam, carbon dioxide, dry powder or water fog for extinction.

P302+352 IF ON SKIN: Wash with plenty of soap and water.

P303+361+353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.

P333+313 If skin irritation or rash occurs: Get medical advice/attention.

P363 Wash contaminated clothing before reuse.

P403+235 Store in a well-ventilated place. Keep cool.

2.3. Other hazards

3.2. Mixtures

WATER THINNABLE POLYACRYLATE CONTAINING HYDROXYL GROUPS 30-60%
CAS-No.:
EC No.:
Classification (67/548/EEC): R43.
Classification (EC 1272/2008): Skin Sens. 1 – H317

SOLVENT NAPHTHA, LIGHT AROMATIC( content of benzene <0.1%) 1-5%
CAS-No.: 64742-95-6
EC No.: 265-199-0
Classification (67/548/EEC):
Xn;R65.
Xi;R37.
N;R51/53.
R10,R66,R67.
Classification (EC 1272/2008):
Flam. Liq. 3 – H226
EUH066
STOT SE 3 – H335, H336
Asp. Tox. 1 – H304
Aquatic Chronic 2 – H411
Registration Number: 01-2119455851-35

2-BUTOXYETHANOL 1-5%
CAS-No.: 111-76-2
EC No.: 203-905-0
Classification (67/548/EEC):
Xn;R20/21/22
Xi;R36/38
Classification (EC 1272/2008):
Acute Tox. 4 – H302
Acute Tox. 4 – H312
Acute Tox. 4 – H332
Skin Irrit. 2 – H315
Eye Irrit. 2 – H319

2-DIMETHYLAMINOETHANOL 1-5%
CAS-No.: 108-01-0
EC No.: 203-542-8
Classification (67/548/EEC):
R10
C;R34
Xn;R20/21/22
Classification (EC 1272/2008):
Flam. Liq. 3 – H226
Acute Tox. 4 – H302
Acute Tox. 4 – H312
Acute Tox. 3 – H331
Skin Corr. 1B – H314
STOT SE 3 – H335

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

4.1. Description of first aid measures

General information: General first aid, rest, warmth and fresh air. Do not give victim anything to drink if they are unconscious.

Inhalation: Remove victim immediately from source of exposure. Provide rest, warmth and fresh air. Get medical attention if any discomfort continues. Place unconscious person on the side in the recovery position and ensure breathing can take place.

Ingestion: DO NOT induce vomiting. Get medical attention immediately. Provide fresh air, warmth and rest, preferably in comfortable upright sitting position.

Skin contact: Remove affected person from source of contamination. Remove contaminated clothing immediately and wash skin with soap and water.

Eye contact: Make sure to remove any contact lenses from the eyes before rinsing. Continue to rinse for at least 15 minutes and get medical attention.

4.2. Most important symptoms and effects, both acute and delayed

General information: If adverse symptoms develop as described the casualty should be transferred to hospital as soon as possible.

4.3. Indication of any immediate medical attention and special treatment needed

No recommendation given, but first aid may still be required in case of accidental exposure, inhalation or ingestion of this chemical. If in doubt, GET MEDICAL ATTENTION PROMPTLY!

5.1. Extinguishing media

Extinguishing media: Extinguish with foam, carbon dioxide, dry powder or water fog. Do not use water jet as an extinguisher, as this will spread the fire.

5.2. Special hazards arising from the substance or mixture

Unusual Fire & Explosion Hazards: FLAMMABLE. Solvent vapours may form explosive mixtures with air.

Specific hazards: When heated and in case of fire, harmful vapours/gases may be formed.

5.3. Advice for firefighters

Special Fire Fighting Procedures: Be aware of danger for fire to re-start. Cool containers exposed to flames with water until well after the fire is out. Do not allow runoff to sewer, waterway or ground.

Protective equipment for fire-fighters: Selection of respiratory protection for fire fighting: follow the general fire precautions indicated in the workplace.

6.1. Personal precautions, protective equipment and emergency procedures

Avoid inhalation of vapours and contact with skin and eyes. Provide adequate ventilation. Do not smoke, use open fire or other sources of ignition. Ensure suitable personal protection (including respiratory protection) during removal of spillages in a confined area.

6.2. Environmental precautions

Avoid discharge into drains, water courses or onto the ground. Contain spillages with sand, earth or any suitable adsorbent material.

Spillages or uncontrolled discharges into watercourses must be IMMEDIATELY alerted to the Environmental Agency or other appropriate regulatory body.

6.3. Methods and material for containment and cleaning up

Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate. Should be prevented from entering drains. Absorb in vermiculite, dry sand or earth and place into containers. Collect spillage in containers, seal securely and deliver for disposal according to local regulations.

6.4. Reference to other sections

For personal protection, see section 8.

7.1. Precautions for safe handling

Observe occupational exposure limits and minimise the risk of inhalation of vapours and mist. Keep away from heat, sparks and open flame.

Avoid spilling, skin and eye contact. Ventilate well, avoid breathing vapours. Use approved respirator if air contamination is above accepted level. Do not eat, drink or smoke when using the product. The Manual Handling Operations Regulations may apply to the handling of containers of this product. To assist employers, the following method of calculating the weight for any pack size is given. Take the pack size volume in litres and multiply this figure by the specific gravity value given in section 9. This will give the net weight of the coating in kilograms. Allowance will then have to be made for the immediate packaging to give an approximate gross weight.

7.2. Conditions for safe storage, including any incompatibilities

Store in closed original container at temperatures between 5°C and 25°C. Keep away from heat, sparks and open flame. Keep containers tightly closed. Keep upright. Store separated from: Oxidising material. Alkalis. Acids.

Storage Class: Flammable liquid storage. The storage and use of this product is subject to the Dangerous Substances and Explosive Atmospheres Regulations (DSEAR). The requirements are given in the HSE Approved Code of Practice and Guidance, Storage of Dangerous Substances: DSEAR. Up to 250 litres of liquids with a flashpoint above 32C but below 55C may be kept in a workroom provided they are kept in closed containers in a marked, fire-resisting cupboard or bin. Larger quantities must be kept in a separate , marked storeroom conforming to the structural requirements contained in the HSE guidance note Storage of Flammable Liquids in Containers.

7.3. Specific end use(s)

The identified uses for this product are detailed in Section 1.2.

Usage Description: Ensure that waste and contaminated materials are collected and removed from the work area as soon as possible in a suitably labelled container.

8.1. Control parameters

8.2. Exposure controls

Protective equipment

Engineering measures: Provide adequate ventilation, including appropriate local extraction, to ensure that the defined occupational exposure limit is not exceeded.

Respiratory equipment: No specific recommendation made, but respiratory protection must be used if the general level exceeds the recommended occupational exposure limit.

Hand protection: Use suitable protective gloves if risk of skin contact. The most suitable glove must be chosen in consultation with the gloves supplier, who can inform about the breakthrough time of the glove material. Barrier cream applied before work may make it easier to clean the skin after exposure, but does not prevent absorption through the skin.

Eye protection: Wear splash-proof eye goggles to prevent any possibility of eye contact.

Other Protection: Wear appropriate clothing to prevent reasonably probable skin contact.

Hygiene measures: No specific hygiene procedures noted, but good personal hygiene practices are always advisable, especially when working with chemicals.

9.1. Information on basic physical and chemical properties

Appearance: Creamy liquid.
Colour: Milky.
Odour: Slight odour.
Solubility: Miscible with water
Initial boiling point and boiling range (°C): approx. 100C
Relative density: approx. 1.08 g/ml @ 20C
Vapour density (air=1): heavier than air
pH-Value, Conc. Solution: Alkaline
Viscosity: approx. 800 DIN 53019/1 mPas 23C
Flash point (°C): 45C CC (Closed cup).
Flammability Limit – Lower(%): Solvent naththa 1.0% by vol., 2-butoxyethanol 1.1% by vol.
Flammability Limit – Upper(%): Solvent naphtha 7.5% by vol., 2-butoxyethanol 10.6% by vol.

9.2. Other information

Volatility Description: Volatile
Volatile By Vol. (%): 55% by weight
Volatile Organic Compound (VOC): 83 g/litre

10.1. Reactivity

No specific reactivity hazards associated with this product.

10.2. Chemical stability

Stable under normal temperature conditions and recommended use.

10.3. Possibility of hazardous reactions

Not determined.

10.4. Conditions to avoid

Avoid heat, flames and other sources of ignition. Avoid contact with acids and oxidising substances.

10.5. Incompatible materials

Materials To Avoid: Strong alkalis. Strong acids. Strong oxidising substances.

10.6. Hazardous decomposition products

Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours.

11.1. Information on toxicological effects

Toxicological information: The material shows a sensitizing effect in conjuction with some complex hydrocarbons such as the Solvent Naphthas through skin absorption, and is considered to be an inherent property of the mixture.

Inhalation: Vapour from this chemical can be hazardous when inhaled. Vapour may irritate respiratory system or lungs.

Ingestion: Liquid irritates mucous membranes and may cause abdominal pain if swallowed.

Skin contact: Acts as a defatting agent on skin. May cause cracking of skin, and eczema. Prolonged or repeated exposure may cause severe irritation. May cause sensitisation by skin contact.

Eye contact: May cause temporary eye irritation.

Health Warnings: May cause sensitisation by skin contact.

Route of entry: Inhalation. Skin absorption. Ingestion. Skin and/or eye contact.

Medical Considerations: Skin disorders and allergies. Avoid vomiting and normal rinse of stomach because of risk of aspiration.

Toxicological information on ingredients.

2-BUTOXYETHANOL (CAS: 111-76-2)

Acute toxicity:
Acute Toxicity (Oral LD50)
1480 mg/kg Rat
Acute Toxicity (Dermal LD50)
435 mg/kg Rabbit

Skin Corrosion/Irritation:
Irritating.

Serious eye damage/irritation:
Moderately Irritating.

Aspiration hazard:
Skin contact
May be absorbed through the skin.

WATER THINNABLE POLYACRYLATE CONTAINING HYDROXYL GROUPS

Toxicological information: Salmonella/microsome test (Ames test). No indication of mutagenic effects.

Respiratory or skin sensitisation:
Skin sensitisation
Local Lymph Node Assay (LLNA) Rat
Epidemiological studies have shown evidence of skin sensitisation. The material shows a sensitizing effect in conjuction with some complex hydrocarbons such as the Solvent Naphthas through skin absorption, and is considered to be an inherent property of the mixture.

Germ cell mutagenicity:
Genotoxicity – In Vitro
Ames Test
Negative.
This substance has no evidence of mutagenic properties.

SOLVENT NAPHTHA, LIGHT AROMATIC (content of benzene <0.1%) (CAS: 64742-95-6)

Acute toxicity:
Acute Toxicity (Oral LD50)
3592 mg/kg Rat
Acute Toxicity (Dermal LD50)
> 3160 mg/kg Rabbit
Acute Toxicity (Inhalation LC50)
> 6.193 mg/l (vapours) Rat 4 hours

Skin Corrosion/Irritation:
Slightly irritating.

Aspiration hazard:
Inhalation: Irritating to respiratory system. In high concentrations, vapours are narcotic and may cause headache, fatigue, dizziness and nausea.
Ingestion: Harmful: danger of serious damage to health by prolonged exposure if swallowed. Repeated exposure may cause skin dryness or cracking.

Ecotoxicity: The product contains substances which are toxic to aquatic organisms and which may cause long term adverse effects in the aquatic environment.

Ecological information on ingredients.

SOLVENT NAPHTHA, LIGHT AROMATIC( content of benzene <0.1%) (CAS: 64742-95-6)

Ecotoxicity: The product contains substances which are toxic to aquatic organisms and which may cause long term adverse effects in the aquatic environment.

12.1. Toxicity

Ecological information on ingredients.

2-BUTOXYETHANOL (CAS: 111-76-2)

LC50 96 hours ~ 1490 mg/l Lepomis macrochirus (Bluegill)

Acute Toxicity – Aquatic Invertebrates
EC50 48 hours ~ 1815 mg/l Daphnia magna

Acute Toxicity – Aquatic Plants
EC50 72 hours > 500 mg/l Scenedesmus subspicatus

SOLVENT NAPHTHA, LIGHT AROMATIC( content of benzene <0.1%) (CAS: 64742-95-6)

Acute Toxicity – Fish
LC50 96 hours ~ 9.22 mg/l Onchorhynchus mykiss (Rainbow trout)

Acute Toxicity – Aquatic Invertebrates
EC50 48 hours ~ 6.14 mg/l Daphnia magna
EC50 96 hours ~ 19 mg/l Freshwater algae

Acute Toxicity – Microorganisms
EC50 1 – 10 mg/l

12.2. Persistence and degradability

Degradability: The product is slowly degradable.

Ecological information on ingredients.

2-BUTOXYETHANOL (CAS: 111-76-2)

Degradability: The product is expected to be biodegradable.

Biodegradation: Degradation (90%)
Biological Oxygen Demand: ~ 0.756 g O2/g substance
Chemical Oxygen Demand: ~ 2.379 g O2/g substance

SOLVENT NAPHTHA, LIGHT AROMATIC( content of benzene <0.1%) (CAS: 64742-95-6)

Degradability: The product is easily biodegradable.

12.3. Bioaccumulative potential

12.4. Mobility in soil

Mobility: The product contains volatile organic compounds (VOC) which will evaporate easily from all surfaces.

12.5. Results of PBT and vPvB assessment

12.6. Other adverse effects

The product contains volatile, organic compounds which have a photochemical ozone creation potential.

General information: Do not allow to enter drains, sewers or watercourses.

13.1. Waste treatment methods

Dispose of waste and residues in accordance with local authority requirements.

Waste Class: When this coating, in its liquid state, as supplied, becomes a waste, it is categorised as hazardous waste, with code 08 01 11* (SOLVENT BASED LIQUID WASTE). Part-used containers, not drained and/or rigorously scraped out and containing dried residues of the supplied coating, are categorised as hazardous waste, with code 08 01 11* (SOLVENT BASED LIQUID WASTE). If mixed with other wastes, the above waste code may not be applicable. Used containers, drained and/or rigorously scraped out and containing dry residues of the supplied coating, are categorised as non-hazardous waste, with code 15 01 02 (plastic packaging) or 15 01 04 (metal packaging).

General This product is packed in accordance with the Limited Quantity Provisions of CDGCPL2, ADR and IMDG.

14.1. UN number

UN No. (ADR/RID/ADN) 1263
UN No. (IMDG) 1263
UN No. (ICAO) 1263

14.2. UN proper shipping name

14.3. Transport hazard class(es)

ADR/RID/ADN Class 1263
ADR/RID/ADN Class Class 3: Flammable liquids.
IMDG Class 3

Transport Labels

14.4. Packing group

ADR/RID/ADN Packing group III
IMDG Packing group III
ICAO Packing group III

14.5. Environmental hazards

14.6. Special precautions for user

EMS F-E, S-E
Tunnel Restriction Code (D/E)

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

Not applicable.

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

UK Regulatory References

The Control of Substances Hazardous to Health Regulations 2002 (S.I 2002 No. 2677) with amendments.

Statutory Instruments

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). Control of Substances Hazardous to Health.

Approved Code Of Practice

Safety Data Sheets for Substances and Preparations. Classification and Labelling of Substances and Preparations Dangerous for Supply.

Dangerous Substances and Explosive Atmospheres Regulations 2002 [L138]

Guidance Notes

Workplace Exposure Limits EH40. CHIP for everyone HSG(108).

EU Legislation

Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments.

National Regulations

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2002. No. 1689.

15.2. Chemical Safety Assessment

No chemical safety assessment has been carried out.

General information

Only trained personnel should use this material.

Revision Comments

Issued in new format for Reach compliance in accordance with EC 1272/2008 Issued in accordance with Annex II to REACH, as amended by Commission Regulation (EU) No. 453/2010 Update for CLP labelling.

Issued By Technical Dept. (P.E.)

Revision Date 27/05/2015

Revision 2

Supersedes date 14/01/2013

SDS No. 11610

Safety Data Sheet Status Approved.

Date Date printed ________________

Signature Initials ______________________

Risk Phrases In Full

R34 Causes burns.

R10 Flammable.

R20/21/22 Harmful by inhalation, in contact with skin and if swallowed.

R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

R65 Harmful: may cause lung damage if swallowed.

R36/38 Irritating to eyes and skin.

R37 Irritating to respiratory system.

R43 May cause sensitisation by skin contact.

R66 Repeated exposure may cause skin dryness or cracking.

R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

R67 Vapours may cause drowsiness and dizziness.

Hazard Statements In Full

H319 Causes serious eye irritation.

H314 Causes severe skin burns and eye damage.

H315 Causes skin irritation.

H226 Flammable liquid and vapour.

H332 Harmful if inhaled.

H302 Harmful if swallowed.

H312 Harmful in contact with skin.

H412 Harmful to aquatic life with long lasting effects.

H304 May be fatal if swallowed and enters airways.

H317 May cause an allergic skin reaction.

H336 May cause drowsiness or dizziness.

H335 May cause respiratory irritation.

EUH066 Repeated exposure may cause skin dryness or cracking.

H331 Toxic if inhaled.

H411 Toxic to aquatic life with long lasting effects.

Disclaimer

This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company’s knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user’s responsibility to satisfy himself as to the suitability of such information for his own particular use.

1.1. Product identifier

Product name TH/W222 – ANTI-GRAFITTI WHITE COLOUR COAT & BONDING PRIMER BASE
Product No. TH/W222/1 – BASE

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses BASE FOR TWO COMPONENT FLOOR COATING

1.3. Details of the supplier of the safety data sheet

Supplier THERMOGUARD UK LTD
Kirkby Street
Hull
HU2 0BE
+44(0)1142 768008
+44(0)1624 825115
sales@thermoguard.co.uk
Contact Person Sales Department – 08.00 – 17.00 hrs Mon – Fri. as above

1.4. Emergency telephone number

+44 (0) 1142 768008 Thermoguard UK Ltd (08.00 – 17.00 hrs Mon – Fri)

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)
Physical and Chemical Hazards Not classified.
Human health Skin Irrit. 2 – H315;Eye Irrit. 2 – H319;Skin Sens. 1 – H317
Environment Aquatic Chronic 2 – H411
Classification (1999/45/EEC) Xi;R36/38. R43. N;R51/53.

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

Human health: The product contains a small amount of sensitising substance which may provoke an allergic reaction among sensitive individuals in contact with skin.

Physical and Chemical Hazards: When handled correctly, undamaged units represent no danger.

2.2. Label elements

Contains REACTION PRODUCT : BISPHENOL A-(EPICHLOROHYDRIN):EPOXY RESIN (NUMBER AVERAGE MW<=700) FORMALDEHYDE, OLIGOMERIC REACTION PRODUCTS WITH 1-CHLORO-2,3-EPOXYPROPANE AND PHENOL OXIRANE, MONO [(C12-14- ALKYLOXY)METHYL] DERIVS Label In Accordance With (EC) No. 1272/2008  

Signal Word Warning

Hazard Statements

H315 Causes skin irritation.

H317 May cause an allergic skin reaction.

H319 Causes serious eye irritation.

H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements

P102 Keep out of reach of children.

P101 If medical advice is needed, have product container or label at hand.

P273 Avoid release to the environment.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P313 Get medical advice/attention.

P501A Dispose of contents/container to special waste collection point

Supplementary Precautionary Statements

P272 Contaminated work clothing should not be allowed out of the workplace.

P261 Avoid breathing vapour/spray.

P264 Wash contaminated skin thoroughly after handling.

P321 Specific treatment (see medical advice on this label).

P302+352 IF ON SKIN: Wash with plenty of soap and water.

P332+313 If skin irritation occurs: Get medical advice/attention.

P333+313 If skin irritation or rash occurs: Get medical advice/attention.

P337 If eye irritation persists:

P362 Take off contaminated clothing and wash before reuse.

P363 Wash contaminated clothing before reuse.

P391 Collect spillage.

Supplemental label information

EUH205 Contains epoxy constituents. May produce an allergic reaction.

2.3. Other hazards

3.2. Mixtures

REACTION PRODUCT : BISPHENOL A-(EPICHLOROHYDRIN):EPOXY RESIN (NUMBER AVERAGE MW<=700) 30-60%
CAS-No.: 25068-38-6
EC No.: 500-033-5
Classification (67/548/EEC):
R43
Xi;R36/38
N;R51/53
Classification (EC 1272/2008):
Skin Irrit. 2 – H315
Eye Irrit. 2 – H319
Skin Sens. 1 – H317
Aquatic Chronic 2 – H411

Barium Sulphate 10-30%
CAS-No.: 7727-43-7
EC No.: 231-784-4
Classification (67/548/EEC): Not classified.
Classification (EC 1272/2008): Not classified.
Registration Number: 01-2119491274-35-0001

FORMALDEHYDE, OLIGOMERIC REACTION PRODUCTS WITH 1-CHLORO-2,3-EPOXYPROPANE AND PHENOL 10-30%
CAS-No.: 9003-36-5
EC No.: 500-006-8
Classification (67/548/EEC):
Xi;R38.
N;R51/53.
R43.
Classification (EC 1272/2008):
Skin Irrit. 2 – H315
Skin Sens. 1 – H317
Aquatic Chronic 2 – H411

Diatomaceous Earth 10-30%
CAS-No.: 61790-53-2
EC No.: 310-127-6
Classification (67/548/EEC): Not classified.
Classification (EC 1272/2008): Not classified.

Calcium Magnesium Silicate 5-10%
CAS-No.: 14807-96-6
EC No.: 238-877-9
Classification (67/548/EEC): Not classified.
Classification (EC 1272/2008):Not classified.

OXIRANE, MONO [(C12-14- ALKYLOXY)METHYL] DERIVS 5-10%
CAS-No.: 68609-97-2
EC No.:
Classification (67/548/EEC):
R43
Xi;R38
Classification (EC 1272/2008):
Skin Irrit. 2 – H315
Skin Sens. 1 – H317

dodecylphenol, ethoxylated <1% CAS-No.: 9014-92-0 EC No.: Classification (67/548/EEC): Xi;R36/38. N;R51/53. Classification (EC 1272/2008): Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Aquatic Chronic 2 - H411 2-METHYLPENTANE-2,4-DIOL <1% CAS-No.: 107-41-5 EC No.: 203-489-0 Classification (67/548/EEC): Xi;R36/38 Classification (EC 1272/2008): Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Alkylphenolethersulfat-sodium salt <1% CAS-No.: 109909-39-9 EC No.: Classification (67/548/EEC): Xi;R41. N;R51/53. Classification (EC 1272/2008): Eye Dam. 1 - H318 Aquatic Chronic 2 - H411 phosphoric acid ester, neutralised <1% CAS-No.: 68954-84-7 EC No.: Classification (67/548/EEC): Xi;R38,R41. N;R51/53. Classification (EC 1272/2008): Skin Irrit. 2 - H315 Eye Dam. 1 - H318 Aquatic Chronic 2 - H411 isotridecylalcohol,ethoxylated,phosphated,compd. with N,N-dimethylcyclohexanamine <1% CAS-No.: 164383-18-0 EC No.: Classification (67/548/EEC): Xi;R36/38. N;R51/53. Classification (EC 1272/2008): Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Aquatic Chronic 2 - H411 nonylphenol, branched, ethoxylated, phosphate <1% CAS-No.: EC No.: Classification (67/548/EEC): Xi;R38,R41. N;R51/53. Classification (EC 1272/2008): Skin Irrit. 2 - H315 Eye Dam. 1 - H318 Aquatic Chronic 2 - H411 The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. [/fusion_toggle][fusion_toggle title="SECTION 4: FIRST AID MEASURES" open="no"]

4.1. Description of first aid measures

General information: General first aid, rest, warmth and fresh air. Do not give victim anything to drink if they are unconscious.

Inhalation: Remove victim immediately from source of exposure. Provide rest, warmth and fresh air. Get medical attention if any discomfort continues. Place unconscious person on the side in the recovery position and ensure breathing can take place.

Ingestion: Immediately give a couple of glasses of water or milk, provided the victim is fully conscious. Do not induce vomiting. Get medical attention if any discomfort continues.

Skin contact: Remove affected person from source of contamination. Wash off promptly and flush contaminated skin with water. Promptly remove clothing if soaked through and flush skin with water. Get medical attention if irritation persists after washing.

Eye contact: Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyes wide apart. Get medical attention immediately. Continue to rinse.

4.2. Most important symptoms and effects, both acute and delayed

General information: If adverse symptoms develop as described the casualty should be transferred to hospital as soon as possible.

4.3. Indication of any immediate medical attention and special treatment needed

No recommendation given, but first aid may still be required in case of accidental exposure, inhalation or ingestion of this chemical. If in doubt, GET MEDICAL ATTENTION PROMPTLY!

5.1. Extinguishing media

Extinguishing media: Non flammable at room temperature, but will burn. Use fire-extinguishing media appropriate for surrounding materials. Fire can be extinguished using: Water spray, fog or mist. Foam, carbon dioxide or dry powder.

5.2. Special hazards arising from the substance or mixture

Specific hazards: When heated and in case of fire, harmful vapours/gases may be formed.

5.3. Advice for firefighters

Special Fire Fighting Procedures: Avoid breathing fire vapours. Containers close to fire should be removed or cooled with water.

Protective equipment for fire-fighters: Self contained breathing apparatus and full protective clothing must be worn in case of fire.

6.1. Personal precautions, protective equipment and emergency procedures

Avoid inhalation of vapours and contact with skin and eyes. Provide adequate ventilation. Wear protective clothing as described in Section 8 of this safety data sheet.

6.2. Environmental precautions

Avoid discharge into drains, water courses or onto the ground. Contain spillages with sand, earth or any suitable adsorbent material. Spillages or uncontrolled discharges into watercourses must be IMMEDIATELY alerted to the Environmental Agency or other appropriate regulatory body.

6.3. Methods and material for containment and cleaning up

Should be prevented from entering drains. Absorb in vermiculite, dry sand or earth and place into containers. Collect spillage in containers, seal securely and deliver for disposal according to local regulations.

6.4. Reference to other sections

For personal protection, see section 8.

7.1. Precautions for safe handling

Avoid inhalation of vapours. Avoid spilling, skin and eye contact. Do not eat, drink or smoke when using the product. Good personal hygiene is necessary. Wash hands and contaminated areas with water and soap before leaving the work site. The Manual Handling Operations Regulations may apply to the handling of containers of this product. For products sold by weight refer to the guide net weight indicated on the container. Allowance will have to be made for the immediate packaging to give an approximate gross weight.

7.2. Conditions for safe storage, including any incompatibilities

Store in tightly closed original container in a dry, cool and well-ventilated place. Store in closed original container at temperatures between 5°C and 25°C. Protect from freezing and direct sunlight. Keep upright.

7.3. Specific end use(s)

The identified uses for this product are detailed in Section 1.2.

Usage Description: Ensure that waste and contaminated materials are collected and removed from the work area as soon as possible in a suitably labelled container.

8.1. Control parameters

8.2. Exposure controls

Protective equipment

Process conditions: Use engineering controls to reduce air contamination to permissible exposure level.

Engineering measures: Provide adequate ventilation. Observe Occupational Exposure Limits and minimise the risk of inhalation of vapours.

Respiratory equipment: No specific recommendation made, but respiratory protection may still be required under exceptional circumstances when excessive air contamination exists.

Hand protection: Use suitable protective gloves if risk of skin contact. The most suitable glove must be chosen in consultation with the gloves supplier, who can inform about the breakthrough time of the glove material. Barrier cream applied before work may make it easier to clean the skin after exposure, but does not prevent absorption through the skin.

Eye protection: Wear approved chemical safety goggles where eye exposure is reasonably probable.

Other Protection: Wear appropriate clothing to prevent reasonably probable skin contact.

Hygiene measures: No specific hygiene procedures noted, but good personal hygiene practices are always advisable, especially when working with chemicals.

Personal protection: Unprotected persons should be kept away from treated areas.

9.1. Information on basic physical and chemical properties

Appearance: Coloured liquid.
Odour: Sweetish.
Solubility: Immiscible with water
Initial boiling point and boiling range (°C): >150 760 mm Hg
Relative density: 1.12 @ 25C
Vapour pressure: Viscosity: 0.90 Pas @ 25 C
Auto Ignition Temperature (°C): >200

9.2. Other information

Volatile By Vol. (%): 0 – 4%
Volatile Organic Compound (VOC): 0 g/litre

10.1. Reactivity

No specific reactivity hazards associated with this product.

10.2. Chemical stability

Stable under normal temperature conditions and recommended use.

10.3. Possibility of hazardous reactions

Hazardous Polymerisation: Will not occur

10.4. Conditions to avoid

Not known.

10.5. Incompatible materials

Materials To Avoid: Strong acids. Bases, alkalis (inorganic). Amines. Mercaptans (thiols).

10.6. Hazardous decomposition products

Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours.

11.1. Information on toxicological effects

Toxicological information: No data recorded.

General information: No specific health warnings noted.

Inhalation: May cause irritation to the respiratory system.

Ingestion: Harmful if swallowed. Ingestion may cause severe irritation of the mouth, the oesophagus and the gastrointestinal tract.

Skin contact: Irritating to skin. May cause sensitisation by skin contact.

Eye contact: Irritating to eyes.

Health Warnings: May cause sensitisation by skin contact. Delayed appearance of the complaints and development of hypersensitivity (difficulty breathing, coughing, asthma) are possible.

Route of entry: Inhalation. Skin absorption. Ingestion. Skin and/or eye contact.

Medical Considerations: Skin disorders and allergies.

Ecotoxicity: There are no data on the ecotoxicity of this product.

12.1. Toxicity

Acute Fish Toxicity

Toxicity to bacteria, algae and higher marine organisms not tested. COD: Not determined

12.2. Persistence and degradability

Degradability: No data available.

12.3. Bioaccumulative potential

Bioaccumulative potential: No data available on bioaccumulation.

12.4. Mobility in soil

Mobility: The product is non-volatile.

12.5. Results of PBT and vPvB assessment

12.6. Other adverse effects

Not determined.

General information: Do not allow to enter drains, sewers or watercourses. Waste to be treated as controlled waste. Disposal to licensed waste disposal site in accordance with local Waste Disposal Authority. When handling waste, consideration should be made to the safety precautions applying to handling of the product. DO NOT reuse containers containing residual product without commercial cleaning

13.1. Waste treatment methods

Waste Class: When this material, in its liquid state, as supplied, becomes a waste, it is categorised as a hazardous waste, with code 08 01 11* (EPOXY BASED LIQUID WASTE). Part-used containers, not drained and/or rigorously scraped out and containing residues of the supplied material, are categorised as hazardous waste, with code 08 01 11* (EPOXY BASED LIQUID WASTE). Ideally this component should be mixed with the appropriate hardener and allowed to react fully to produce a solid waste. Neutralised empty packages, are categorised as non-hazardous waste, with code 15 01 02(plastic packaging) or 15 01 04 (metal packaging).

General: This product is packed in accordance with the Limited Quantity Provisions of CDGCPL2, ADR and IMDG.

14.1. UN number

UN No. (ADR/RID/ADN) 3082
UN No. (IMDG) 3082

14.2. UN proper shipping name

Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

14.3. Transport hazard class(es)

ADR/RID/ADN Class 9
ADR/RID/ADN Class Class 9: Environmentally hazardous substance, liquid, N.O.S. contains: epoxy constituents
ADR/RID/ADN Subsidiary Risk HAZARD ID 90
IMDG Class 9
ICAO Class/Division 9

Transport Labels

14.4. Packing group

ADR/RID/ADN Packing group III
IMDG Packing group III
ICAO Packing group III

14.5. Environmental hazards

Environmentally Hazardous Substance/Marine Pollutant

14.6. Special precautions for user

EMS F-A S-F
Tunnel Restriction Code (E)

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

Not applicable.

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

UK Regulatory References

The Control of Substances Hazardous to Health Regulations 2002 (S.I 2002 No. 2677) with amendments.

Statutory Instruments

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). Control of Substances Hazardous to Health.

Approved Code Of Practice

Safety Data Sheets for Substances and Preparations. Classification and Labelling of Substances and Preparations Dangerous for Supply.

Dangerous Substances and Explosive Atmospheres Regulations 2002 [L138]

Guidance Notes

Workplace Exposure Limits EH40. CHIP for everyone HSG(108).

EU Legislation

Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments.

National Regulations

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2002. No. 1689.

15.2. Chemical Safety Assessment

No chemical safety assessment has been carried out.

Revision Comments

Issued in new format for Reach compliance in accordance with EC 1272/2008 Issued in accordance with Annex II to REACH, as amended by Commission Regulation (EU) No. 453/2010 Update for CLP labelling.

Issued By Technical Dept. (P.E.)

Revision Date 18/05/2015

Revision 2

Supersedes date 25/10/2012

SDS No. 11613

Safety Data Sheet Status Approved.

Date Date printed ____________________

Signature Initials ____________________

Risk Phrases In Full

R36/38 Irritating to eyes and skin.

R38 Irritating to skin.

R43 May cause sensitisation by skin contact.

NC Not classified.

R41 Risk of serious damage to eyes.

R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Hazard Statements In Full

H318 Causes serious eye damage.

H319 Causes serious eye irritation.

H315 Causes skin irritation.

H317 May cause an allergic skin reaction.

H411 Toxic to aquatic life with long lasting effects.

Disclaimer

This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company’s knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user’s responsibility to satisfy himself as to the suitability of such information for his own particular use.

1.1. Product identifier

Product name TH/WB101 – FLAME RETARDANT ANTI GRAFFITI – ACTIVATOR
Product No. TH/WB101/T – ACTIVATOR

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses ACTIVATOR FOR TWO COMPONENT ANTI-GRAFFITI COATING For use as an an anti graffiti coating over Thermoguard Wallcoat or Thermoguard SFR Dualcoat.

Uses advised against NOT SUITABLE FOR FOR USE IN HOMEWORKER (DIY) APPLICATIONS

1.3. Details of the supplier of the safety data sheet

Supplier THERMOGUARD UK LTD
Kirkby Street
Hull
HU2 0BE
+44(0)1142 768008
+44(0)1624 825115
sales@thermoguard.co.uk
Contact Person Sales Department – 08.00 – 17.00 hrs Mon – Fri. as above

1.4. Emergency telephone number

+44 (0) 1142 768008 Thermoguard UK Ltd (08.00 – 17.00 hrs Mon – Fri)

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)
Physical and Chemical Hazards Not classified.
Human health Acute Tox. 4 – H332;Skin Sens. 1 – H317;STOT SE 3 – H335
Environment Not classified.
Classification (1999/45/EEC) Xn;R20. Xi;R37. R43.
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

Human health: Contains non-volatile isocyanate. Heating may generate vapours which irritate the respiratory system, cause asthmatic breathing, breathlessness and risk of development of respiratory allergy.

2.2. Label elements

Contains Hexamethylene-1,6- diisocyanate homopolymer

Label In Accordance With (EC) No. 1272/2008

Signal Word Warning

Hazard Statements

H317 May cause an allergic skin reaction.

H332 Harmful if inhaled.

H335 May cause respiratory irritation.

Precautionary Statements

P102 Keep out of reach of children.

P101 If medical advice is needed, have product container or label at hand.

P271 Use only outdoors or in a well-ventilated area.

P262 Do not get in eyes, on skin, or on clothing.

P261 Avoid breathing vapours.

P312 Call a POISON CENTER or doctor/physician if you feel unwell.

P405 Store locked up.

P501 Dispose of contents/container in accordance with national regulations.

Supplementary Precautionary Statements

P302+352 IF ON SKIN: Wash with plenty of soap and water.

P304+340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P333+313 If skin irritation or rash occurs: Get medical advice/attention.

P363 Wash contaminated clothing before reuse.

P321 Specific treatment (see medical advice on this label).

P403+233 Store in a well-ventilated place. Keep container tightly closed.

Supplemental label information

EUH204 Contains isocyanates. May produce an allergic reaction.

2.3. Other hazards

3.2. Mixtures

Hexamethylene-1,6- diisocyanate homopolymer 30-60%
CAS-No.: 28182-81-2
EC No.: 931-274-8
Classification (67/548/EEC):
Xn;R20.
Xi;R37.
R43.
Classification (EC 1272/2008):
Acute Tox. 4 – H332
Skin Sens. 1 – H317
STOT SE 3 – H335
Registration Number: 01-2119485796-17-0002

Hexamethylene-1,6-diisocyanate homopolymer 30-60%
CAS-No.: 28182-81-2
EC No.: 500-060-2
Classification (67/548/EEC): R43.
Classification (EC 1272/2008): Skin Sens. 1 – H317

HEXAMETHYLENE-DI-ISOCYANATE <1% CAS-No.: 822-06-0 EC No.: 212-485-8 Classification (67/548/EEC): T;R23 R42/43 Xi;R36/37/38 Classification (EC 1272/2008): Acute Tox. 4 - H302 Acute Tox. 1 - H330 Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Resp. Sens. 1 - H334 Skin Sens. 1 - H317 STOT SE 3 - H335 The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. [/fusion_toggle][fusion_toggle title="SECTION 4: FIRST AID MEASURES" open="no"]

4.1. Description of first aid measures

General information: Remove soiled, soaked clothing immediately. Remove affected person from source of contamination.

Inhalation: Fresh air and rest. Get medical attention if any discomfort continues. Show this sheet to the doctor

Ingestion: DO NOT INDUCE VOMITING! Do not give anything to drink Rinse nose, mouth and throat with water.

Skin contact: Immediately remove contaminated clothing. Wash skin with soap and water. Continue to rinse for at least 15 minutes. Contact physician if irritation continues or sores develop.

Eye contact: Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyelids widely. If irritation persists: Seek medical attention and bring along these instructions.

4.2. Most important symptoms and effects, both acute and delayed

General information: The severity of the symptoms described will vary dependant of the concentration and the length of exposure.

Inhalation: Irritation of nose, throat and airway.

Ingestion: No specific symptoms noted.

Skin contact: Skin irritation.

Eye contact: Irritating and may cause redness and pain.

4.3. Indication of any immediate medical attention and special treatment needed

No recommendation given, but first aid may still be required in case of accidental exposure, inhalation or ingestion of this chemical. If in doubt, GET MEDICAL ATTENTION PROMPTLY!

5.1. Extinguishing media

Extinguishing media: Extinguish with foam, carbon dioxide, dry powder or water fog.

Unsuitable extinguishing media: Do not use water as an extinguisher.

5.2. Special hazards arising from the substance or mixture

Specific hazards: Combustible material. When heated and in case of fire, toxic vapours/gases may be formed.

5.3. Advice for firefighters

Special Fire Fighting Procedures: Keep up-wind to avoid fumes. Use water SPRAY only to cool containers! Do not put water on leaked material.

Protective equipment for fire-fighters: Self contained breathing apparatus and full protective clothing must be worn in case of fire.

6.1. Personal precautions, protective equipment and emergency procedures

Avoid inhalation of vapours and contact with skin and eyes. Provide adequate ventilation. Use protective gloves, goggles and suitable protective clothing.

6.2. Environmental precautions

Contain spillages using bunding. Do not allow to enter drains, sewers or watercourses.

6.3. Methods and material for containment and cleaning up

Should be prevented from entering drains. Absorb in vermiculite, dry sand or earth and place into containers. Collect spillage in containers, seal securely and deliver for disposal according to local regulations. Flush contaminated area with plenty of water.

6.4. Reference to other sections

For personal protection, see section 8. Collect and dispose of spillage as indicated in section 13.

7.1. Precautions for safe handling

Mechanical ventilation or local exhaust ventilation is required. Avoid inhalation of vapours. Avoid spilling, skin and eye contact. Avoid contact with water or humidity Comply with instructions for use (refer to technical sheet) Good personal hygiene is necessary. Wash hands and contaminated areas with water and soap before leaving the work site. The Manual Handling Operations Regulations may apply to the handling of containers of this product. To assist employers, the following method of calculating the weight for any pack size is given. Take the pack size volume in litres and multiply this figure by the specific gravity value given in section 9. This will give the net weight of the coating in kilograms. Allowance will then have to be made for the immediate packaging to give an approximate gross weight.

7.2. Conditions for safe storage, including any incompatibilities

Store in closed original container at temperatures between 5°C and 25°C. Keep containers tightly closed. Keep upright. Store separated from: Oxidising material. Alkalis. Acids.

7.3. Specific end use(s)

The identified uses for this product are detailed in Section 1.2.

Usage Description: Ensure that waste and contaminated materials are collected and removed from the work area as soon as possible in a suitably labelled container.

8.1. Control parameters

8.2. Exposure controls

Protective equipment

Engineering measures: No specific ventilation requirements noted, except this product must not be used in a confined space without good ventilation.

Respiratory equipment: No specific recommendation made, but respiratory protection may still be required under exceptional circumstances when excessive air contamination exists.

Hand protection: Protective gloves must be used if there is a risk of direct contact or splash. The most suitable glove must be chosen in consultation with the gloves supplier, who can inform about the breakthrough time of the glove material. Nitrile gloves are recommended. Barrier cream applied before work may make it easier to clean the skin after exposure, but does not prevent absorption through the skin.

Eye protection: Wear approved, tight fitting safety glasses where splashing is probable.

Other Protection: Wear suitable protective clothing as protection against splashing or contamination.

Hygiene measures: No specific hygiene procedures noted, but good personal hygiene practices are always advisable, especially when working with chemicals.

9.1. Information on basic physical and chemical properties

Appearance: Clear, yellowish liquid.
Colour: Light (or pale).
Odour: Slight odour.
Solubility: Miscible with water
Initial boiling point and boiling range (°C): Not measurable (owing to decomposition at > 150C)
Relative density: approx. 1.14 @ 20 °C
Vapour pressure: Hexamethylene-1, 6-diisocyanate = 0.014 mbar 25C
Viscosity: approx. 1200 DIN 53019/1 mPas 23C
Flash point (°C): > 120C OC (Open cup).

9.2. Other information

Volatile By Vol. (%): zero
Volatile Organic Compound (VOC): 0 g/litre

10.1. Reactivity

Reaction with: Alcohols, glycols. Amines. Bases Protic solvents Water and aqueous solutions with great release of CO2, and hence risk of a pressure build-up in confined areas, and forms an insoluble solid precipitate.

10.2. Chemical stability

Stable under normal temperature conditions and recommended use.

10.3. Possibility of hazardous reactions

Not determined.

10.4. Conditions to avoid

Avoid contact with water.

10.5. Incompatible materials

Materials To Avoid: Water, steam, water mixtures.

10.6. Hazardous decomposition products

Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours.

11.1. Information on toxicological effects

Toxicological information: No data recorded.

General information: Preparation contains small volumes of isocyanate which may cause allergic reaction and irritation of respiratory system.

Inhalation: Vapours may irritate the respiratory system and cause coughing, asthmatic breathing and breathlessness. May cause sensitisation by inhalation.

Ingestion: No harmful effects expected in amounts likely to be ingested by accident.

Skin contact: May cause sensitisation by skin contact.

Eye contact: May cause temporary eye irritation.

Route of entry: Inhalation. Skin absorption. Ingestion. Skin and/or eye contact.

Medical Considerations: Skin disorders and allergies.

Specific effects: Frequent inhalation of vapours, may cause respiratory allergy.

Ecotoxicity: The product is not expected to be toxic to aquatic organisms.

12.1. Toxicity

Acute Fish Toxicity
Toxicity to bacteria, algae and higher marine organisms not tested.

12.2. Persistence and degradability

Degradability: The product is not expected to be biodegradable.

12.3. Bioaccumulative potential

Bioaccumulative potential: The product is not bioaccumulating.

12.4. Mobility in soil

Mobility: The product hardens to a solid immobile substance.

12.5. Results of PBT and vPvB assessment

Not Classified as PBT/vPvB by current EU criteria.

12.6. Other adverse effects

Not determined.

General information: Do not allow to enter drains, sewers or watercourses. Waste is classified as hazardous waste. Disposal to licensed waste disposal site in accordance with the local Waste Disposal Authority.

13.1. Waste treatment methods

Empty containers may be disposed of after neutralising any product remaining on the walls of the container with a mixture of water, ammonia and liquid soap.

Waste Class: When this material, in its liquid state, as supplied, becomes a waste, it is categorised as hazardous waste, with EWC code: 08 05 01 (WASTE ISOCYANANTES). Part-used containers, and not drained and/or rigorously scraped out containers, are categorised as hazardous waste, with EWC code 08 05 01 (WASTE ISOCYANATES). Ideally this component should be mixed with the appropriate resin base and allowed to react fully producing a solid non hazardous waste. Transfering some, ready to use, mixed Base/Activator to the Activator package and mixing again should ensure that any Activator residue will fully react and harden. The drained and rigorously scraped out container can then be catagorised as non-hazardous waste with code 15 01 02(plastic packaging) or 15 01 04 (metal packaging). If mixed with other wastes, the above waste code may not be applicable.

General: The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA, ADR/RID).

14.1. UN number

Not applicable.

14.2. UN proper shipping name

No information required.

14.3. Transport hazard class(es)

No information required.

14.4. Packing group

No information required.

14.5. Environmental hazards

Environmentally Hazardous Substance/Marine Pollutant: No.

14.6. Special precautions for user

No information required.

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

Not applicable.

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

UK Regulatory References

The Control of Substances Hazardous to Health Regulations 2002 (S.I 2002 No. 2677) with amendments.

Statutory Instruments

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). Control of Substances Hazardous to Health.

Approved Code Of Practice

Safety Data Sheets for Substances and Preparations. Classification and Labelling of Substances and Preparations Dangerous for Supply.

Dangerous Substances and Explosive Atmospheres Regulations 2002 [L138]

Guidance Notes

Workplace Exposure Limits EH40. CHIP for everyone HSG(108).

EU Legislation

Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments.

National Regulations

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2002. No. 1689.

15.2. Chemical Safety Assessment

No chemical safety assessment has been carried out.

General information: Only trained personnel should use this material.

Revision Comments: Issued in new format for Reach compliance in accordance with EC 1272/2008 Issued in accordance with Annex II to REACH, as amended by Commission Regulation (EU) No. 453/2010 Update for CLP labelling.

Issued By Technical Dept. (P.E.)

Revision Date 27/05/2015

Revision 2

Supersedes date 14/01/2013

SDS No. 11609

Safety Data Sheet Status Approved.

Date Date printed ____________________

Signature Initials ____________________

Risk Phrases In Full

R20 Harmful by inhalation.

R36/37/38 Irritating to eyes, respiratory system and skin.

R37 Irritating to respiratory system.

R42/43 May cause sensitisation by inhalation and skin contact.

R43 May cause sensitisation by skin contact.

R23 Toxic by inhalation.

Hazard Statements In Full

H319 Causes serious eye irritation.

H315 Causes skin irritation.

H330 Fatal if inhaled.

H332 Harmful if inhaled.

H302 Harmful if swallowed.

H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.

H317 May cause an allergic skin reaction.

H335 May cause respiratory irritation.

Disclaimer

This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company’s knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user’s responsibility to satisfy himself as to the suitability of such information for his own particular use.

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